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Mere Teacher · Previous Year Questions
JEE Main Chemistry · Alcohols, Phenols & Ethers · Set 12 (Q331-360)
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331.
When formic acid is heated with concentrated H2SO4, the gas evolved is
(1)only CO2
(2)only CO
(3)a mixture of CO and CO2
(4)a mixture of SO2 and CO2.
332.
Identify (A) in the following reaction sequence: Gives Positive lodoform test (A)→(ii)H+,H2O(3)Conc.H2SO4/Δ(i)CH3MgBr(B)⟶O3/Zn,H2O
(1)
(2)
(3)
(4)
333.
Identify ∘C ' in the following:
(1)Water
(2)Ethanol
(3)Propanone
(4)Cumene hydroperoxide
334.
In the following sequence of reactions, CH3Br→KCNA→H3O+B→LiAlH4C The end product C is
(1)methane
(2)ethyl alcohol
(3)acetone
(4)acetaldehyde.
335.
The appropriate reagent for the following transformation is
(1)Zn−Hg/HCl
(2)H2N−NH2,KOH/ ethylene glycol
(3)Ni/H2
(4)NaBH4
336.
The major product in the following conversion is :
(1)
(2)
(3)
(4)
337.
The product "A" in the above reaction is:
(1)
(2)
(3)
(4)
338.
When CH2=CH−O−CH2−CH3 reacts with one mole of HI, one of the products formed is
(1)ethane
(2)ethanol
(3)iodoethene
(4)ethanal.
339.
Which one of the following reactions is NOT possible?
(1)
(2)
(3)
(4)
340.
Propene, CH3CH=CH2 can be converted into 1‐propanol by oxidation. Indicate which set of reagents amongst the following is ideal for the above conversion?
(1)KMnO4 (alkaline)
(2)Osmium tetroxide
(3)B2H6 and alk.H2O2
(4)O3/Zn
341.
CH3−CH2−CH2−Br+NaOH→C2H5OHProduct’A’
Consider the above reactions, identify product B and product C.
(1)B= 1-Propanol C=2-Propanol
(2)B=C=2-Propanol
(3)B= 2-Propanol C= 1-Propanol
(4)B=C= 1-Propanol
342.
The intramolecular hydrogen bonding is present in
(1)phenol
(2)Benzoic acid
(3)para-Nitrophenol
(4)2-Hydroxybenzoic Acid
343.
Reaction of withRMgXleadsto the formation of
(1)RCH2CH2OH
(2)RCHOHCH3
(3)RCHOHR
(4)(H3C)2CH−CH2−OH
344.
Ethylene oxide when treated with Grignard reagent yields
(1)primary alcohol
(2)secondary alcohol
(3)tertiary alcohol
(4)cyclopropyl alcohol.
345.
The heating of phenyl methyl ether with HI produces an aromatic compound A which on treatment with conc. HNO3 gives B.A and B respectively are,
(1)methanol, ethanoic acid
(2)picric acid, phenol
(3)iodobenzene, 1-iodo-4-nitrobenzene
(4)phenol, picric acid.
346.
The products X and Z in the following sequence are
(1)iso-propyl benzene and acetone
(2)cumene peroxide and acetone
(3)iso-propyl benzene and iso-propyl alcohol
(4)phenol and acetone.
347.
Identify the major product formed from the following reaction sequence
(1)
(2)
(3)
(4)
348.
The compounds A and B in the following reaction are, respectively:
(1)A = Benzyl alcohol, B = Benzyl cyanide
(2)A = Benzyl chloride, B = Benzyl cyanide
(3)A = Benzyl alcohol, B = Benzyl isocyanide
(4)A = Benzyl chloride, B = Benzyl isocyanide
349.
In the following reaction, C6H5CH2Br 1. Mg Ether2. H3O+X, the product 'X' is :
(1)C6H5CH2OCH2C6H5
(2)C6H5CH2OH
(3)C6H5CH3
(4)C6H5CH2CH2C6H5
350.
Which of the following compound gives pink colour on reaction with phthalic anhydride in conc.H2SO4followed by treatment with NaOH?
(1)
(2)
(3)
(4)
351.
Which of the following compounds with molecular formula, C5H10 yields acetone on ozonolysis?
(1)2-methyl-2-butene
(2)3-methyl-1-butene
(3)Cyclopentane
(4)2-methyl-1-butene
352.
The major product in the given reaction is
(1)
(2)
(3)
(4)
353.
A compound 'X' is acidic and it is soluble in NaOH solution, but insoluble in NaHCO3 solution. Compound 'X' also gives violet colour with neutral FeCl3 solution. The compound 'X' is :
(1)
(2)
(3)
(4)
354.
Consider the above reaction sequence and identify the major product P.
(1)Methoxymethane
(2)Methanoic acid
(3)Methanal
(4)Methane
355.
Consider the above reaction, the major product 'P' is:
(1)
(2)
(3)
(4)
356.
When the vapours of tertiary butyl alcohol are passed through heated copper at 573K, the product formed is
(1)but-2-ene
(2)2-butanone
(3)2-methyl propene
(4)butanal.
357.
Given below are two statements: Statement I : Piciric acid is 2,4,6 - trinitrotoluene. Statement II : Phenol - 2,4 - disulphonic acid is treated with Conc. HNO3 to get picric acid. In the light of the above statements, choose the most appropriate answer from the options given below :
(1)Statement I is incorrect but Statement II is correct
(2)Both Statement I and Statement II are incorrect
(3)Statement I is correct but Statement II is incorrect
(4)Both Statement I and Statement II are correct
358.
Which of the following is the major product, when p− cresol is treated with zinc dust?
(1)Toluene
(2)Heptane
(3)Methyl cyclohexanol
(4)Methyl cyclohexane
359.
Main Products formed during a reaction of 1 -methoxy naphthalene with hydroiodic acid are:
(1)and CH3OH
(2)and CH3I
(3)and CH3OH
(4)and CH3I
360.
The major product of the following reaction contains _______ bromine atom(s).