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Mere Teacher · Previous Year Questions
JEE Main Chemistry · Alcohols, Phenols & Ethers · Set 9 (Q241-270)
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241.
Acetophenone cannot be prepared easily starting from
(1)C6H5CH(OH)CH3
(2)C6H5CH3
(3)C6H5C≡CH
(4)C6H6
242.
The reagent with which both acetaldehyde and acetone react is
(1)Fehling’s solution
(2)I2/NaOH
(3)Tollens’ reagent
(4)carbonic acid.
243.
When a mixture of calcium benzoate and calcium acetate is dry distilled, the resulting compound is
(1)acetophenone
(2)benzaldehyde
(3)benzophenone
(4)acetaldehyde.
244.
Hex-4-ene-2-ol on treatment with PCC gives 'A'. 'A1 on reaction with sodium hypoiodite gives 'B', which on further heating with soda lime gives 'C'. The compound 'C' is
(1)2- pentene
(2)proponaldehyde
(3)2-butene
(4)4-methylpent-2-ene
245.
The major product formed in the following reaction is :
(1)CH3−C(CH3)=CH−CH2CH3
(2)(CH3)2C=C(CH3)2
(3)(CH3)2C=CH−CH3
(4)CH3−C(CH3)2−CH=CH2
246.
Most stable product of the following reaction is:
(1)
(2)
(3)
(4)
247.
Compound I is heated with Cone. HI to give a hydroxy compound A which is further heated with Zn dust to give compound B. Identify A and B.
(1)
(2)
(3)
(4)
248.
The major product (P) of the given reaction is(where, Me is -CH3)
(1)
(2)
(3)
(4)
249.
The major products Y and Z in the following reactions are
(1)
(2)
(3)
(4)
250.
The major product of the following reaction sequence is
(1)
(2)
(3)
(4)
251.
Acetic acid is treated with Ca(OH)2 and the product so obtained is subjected to dry distillation. The final product is
(1)propanal
(2)ethanol
(3)ethanal
(4)propanone.
252.
Identify the major products A and B respectively in the following set of reactions.
(1)
(2)
(3)
(4)
253.
Major product formed in the following reaction is a mixture of:
(1)
(2)
(3)
(4)
254.
A and B are in the given reaction?
(1)
(2)
(3)
(4)
255.
On heating glycerol with conc. H2SO4, a compound is obtained which has bad odour. The compound is
(1)acrolein
(2)formic acid
(3)allyl alcohol
(4)glycerol sulphate.
256.
Compounds P and R in the following reaction are : CH3CHO(i) CH3MgBr(ii) H3O+Pconc. H2SO4heatQ (i) B2H6(ii) H2O2/OH−R
(1)position isomers
(2)functional isomers
(3)metamers
(4)identical.
257.
What is the major product "P" of the following reaction ?
(1)
(2)
(3)
(4)
258.
Math the following acids with their pKa values:
A B C D
(1)iii iv i ii
(2)ii i iii iv
(3)iii i iv ii
(4)iv ii iii i
259.
Phenol in presence of sodium hydroxide reacts with chloroform to form salicylaldehyde. The reaction is known as
(1)Kolbe's reaction
(2)Reimer-Tiemann reaction
(3)Stephen reaction
(4)Etard reaction.
260.
Which alkene on ozonolysis gives CH3CH2CHO and ?
(1)CH3CH2CH=C(CH3)2
(2)CH2CH2CH == CHCH2CH3
(3)CH3CH2CH == CHCH3
(4)CH3−C(CH3)=CHCH3
261.
Give correct sequences of reaction for following conversion :
(1)DIBAL –H, NaBH4, H3O⊕/Δ
(2)H3O⊕/Δ, NaBH4, DIBAL–H
(3)NaBH4, DIBAL–H, H3O⊕/Δ
(4)DIBAL–H, H3O⊕/Δ, NaBH4
262.
In the given conversion the compound A is:
(1)
(2)
(3)
(4)
263.
Identify A and B in the chemical reaction? HClA (Major) HCldryacetoneB (Major)
(1)
(2)
(3)
(4)
264.
The major product formed in the following reaction sequence is
(1)
(2)
(3)
(4)
265.
The organic compound that gives following qualitative analysis is: Test Inference (1)Dil. HCl Insoluble (2)NaOH Solution soluble (3)Br2/Water Decolourization
(1)
(2)
(3)
(4)
266.
The major product of following reaction is : R–C≡N (1) AlH(i- Bu)2(2) H2O ?
(1)RCONH2
(2)RCH2NH2
(3)RCHO
(4)RCOOH
267.
Which of the following belongs to benzylic alcohol type?
(1)1-Phenyl-2-Propanol
(2)1-Pheny - 1-Propanol
(3)4-Phenyl-but-3-ene-2-ol
(4)2-Methyl- but-3-ene-2-ol
268.
An organic compound ’A’(C9H10O) when treated with conc. HIundergoes cleavage to yield compounds ’B’ and ’C’. ’B’ gives yellow precipitate with AgNO3 where as ’C’ tautomerizes to ’D’. ’D’ gives positive iodoform test. ’A’ could be
(1)
(2)
(3)
(4)
269.
Consider the above reaction, the major product "P" formed is :-
(1)
(2)
(3)
(4)
270.
Isobutylene on hydroboration followed by oxidation with hydrogen peroxide in presence of base yields