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Mere Teacher · Previous Year Questions
JEE Main Chemistry · Aldehydes & Ketones · Set 9 (Q241-270)
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241.
Assertion : Dimethylsulphide is commonly used for the reduction of an ozonide of an alkene to get the carbonyl compounds Reason : It reduces the ozonide giving water soluble dimethyl sulphoxide and excess of it evaporates
(1)Assertion is True, Reason is True; Reason is a correct explanation for Assertion.
(2)Assertion is True, Reason is True; Reason is NOT a correct explanation for Assertion.
(3)Assertion is True, Reason is False.
(4)Assertion is False, Reason is True.
242.
What is the major product of the following reaction?
(1)
(2)
(3)
(4)
243.
Which will have the highest enol content ?
(1)
(2)
(3)
(4)
244.
The compound that yields only ketonic compound/s on ozonolysis is
(1)but-2-ene
(2)pent-2ene
(3)2,3-dimethylbut-2-ene
(4)2-methylbut-2-ene,
245.
The major product in the following reaction sequence is
(1)
(2)
(3)
(4)
246.
Which of the following conditions or reaction sequence will NOT give acetophenone as the major product ?
(1)C6H5−C(=O)−H+CH3MgBr
(2)H3C−C(=O)−H+C6H5MgBr
(3)C6H5−C(=O)−OC2H5+2CH3MgBr
(4)C6H5−C(=O)−Cl+CH3MgBr+CdCl2
247.
Benzene on reaction with acetyl chloride in the presence of anhydrous AlCl3 gave the product P. The product P on reaction with methyl magnesium bromide followed by treatment with water furnished the product Q. The molecular formula of Q is
(1)C8H10O
(2)C8H8O
(3)C9H12O
(4)C9H10O
248.
Identify X,Y,Z in the following reaction sequence
(1)
(2)
(3)
(4)
249.
X and Y in the following reactions are
(1)
(2)
(3)
(4)
250.
Identify ' A ' in the following reaction:
(1)
(2)CH3−C(CH3)=N−NH2
(3)CH3−C(C2H5)=N−NH2
(4)
251.
Predict the correct intermediate and product in the following reaction. [NEET 2017] H3C−C≡CHH2O,H2SO4HgSO4 Intermediate → Product (A) (B)
(1)A=H3C−C(SO4)=CH2;B=H3C−C(=O)−CH3
(2)A=H3C−C(OH)=CH2;B=H3C−C(SO4)=CH2
(3)A=H3C−C(=O)−CH3;B=H3C−C≡CH
(4)A=H3C−C(OH)=CH2;B=H3C−C(=O)−CH3
252.
Identify substrate ' A ' in the following reaction. 2nADimethylcadmium2nPropanone+nCadmium chloride
(1)Ethyl chloride
(2)Ethylene dichloride
(3)Ethanoyl chloride
(4)Ethylidene dichloride
253.
Identify the reagents A and B respectively in the following reactions. CH3COOHACH3COClBCH3CHO
(1)SOCl2,H2/Pd−BaSO4
(2)H2/Pd−BaSO4,SOCl2
(3)SOCl2,H2O2
(4)SOCl2,O5O4
254.
The major product (P) in the following reaction is:
(1)Ph−CH(OH)−COO−K+
(2)Ph−CH(OH)−CH2OH
(3)Ph−C(=O)−COO−K+
(4)Ph−C(=O)−CH2OH
255.
Match List - I with List -II.
Choose the correct answer from options given below:
(1)A-(III), (B)-(IV), (C)-(I), (D)-(II)
(2)A-(IV), (B)-(II), (C)-(I), (D)-(III)
(3)A-(IV), (B)-(II), (C)-(III), (D)-(I)
(4)A-(III), (B)-(IV), (C)-(II), (D)-(I)
256.
The reagent needed for converting is :
(1)Cat. Hydrogenation
(2)H2/Lindlar Cat.
(3)Li/NH3
(4)LiAlH4
257.
'R' formed in the following sequence of reaction is: o
(1)
(2)
(3)
(4)
258.
The ' X ' in the following conversion is H3CCH2COOH→xCH3CHBrCOOH
(1)(i) Br2/P red, (ii) H2O
(2)(i) Br2/CCl4, (ii) H2O
(3)Br2/OH−
(4)PBr3
259.
L-isomer of a compound 'A' (C4H8O4) gives a positive test with [Ag(NH3)2]+. Treatment of 'A' with acetic anhydride yield triacetate derivative. Compound 'A' produces an optically active compound (b) and an optically inactive compound (c) on treatment with bromine water and HNO3 respectively, compound (a) is:
(1)
(2)
(3)
(4)
260.
Identify the compound ' D ' in above mentioned series of reactions.
(1)
(2)
(3)
(4)
261.
The major products P and Q in the following reaction sequences are
P Q
(1)3-methylpentanol Ethanol
(2)3-methylpentanal Ethanal
(3)3-methylbutanol Ethanol
(4)3-methylbutanal Ethanal
262.
Which of the following is an example of conjugated diketone?
(1)CH3−C(=O)−CH2−CH2−CH2−C(=O)−CH3
(2)
(3)
(4)
263.
Isobutyraldehyde on reaction with formaldehyde and K2CO3 gives compound ‘A’ Compound 'A' reacts with KCN and yields compound 'B' which on hydrolysis gives a stable compound 'C'. The compound 'C' is
(1)HO−CH2−C(CH3)(CH3OH)−CH(OH)−COOH
(2)HO−CH2CH2−CH(CH3)−CH(OH)−COOH
(3)
(4)
264.
In the following reactions, products A and B are: HdilNaOH(A) (A)H3O+(B)
(1)
(2)
(3)
(4)
265.
The structures of major products A, B and C in the following reaction are sequence.
(1)
(2)
(3)
(4)
266.
Which of the following compound can give positive iodoform test when treated with aqueous KOH solution followed by potassium hypoiodite.
(1)CH3CH2−C(Cl)2−CH3
(2)
(3)CH3CH2−C(=O)−CH2CH3
(4)CH3CH2CH2CHO
267.
The major product of the following reaction is :
(1)CH3−CH(CH3)−CH(Br)−CH2OH
(2)CH3−CH(CH3)−CH2−CH2−CH2OH
(3)CH3−CH(CH3)−CH2−CH2OH
(4)CH3−CH(CH3)−CH2−CH2−Cl
268.
The correct set of reagents which convert acetylene to but-2-enal are
(1)H2SO4,NaOH
(2)H2O/Hg2+/H+, dil. NaOH
(3)H2O/H+, conc. NaOH
(4)H2O,KMnO4/OH−
269.
Two moles of benzaldehyde and one mole of acetone under alkaline conditions using aqueous NaOH after heating gives x as the major product. The number of π bonds in the product x is _____
270.
In the given reaction
(Where Et is -C2H5) The number of chiral carbon/s in product A is