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Mere Teacher · Previous Year Questions
JEE Main Chemistry · Amines · Set 5 (Q121-150)
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121.
Given below are two statements : Statement (I) : All the following compounds react with p-toluenesulfonyl chloride. C6H5NH2(C6H5)2NH(C6H5)3N Statement (II) : Their products in the above reaction are soluble is aqueous NaOH. In the light of the above statements, choose the correct answer from the options given below
(1)Statement I is false but Statement II is true
(2)Statement I is true but Statement II is false
(3)Both Statement I and Statement II are true
(4)Both Statement I and Statement II are false
122.
Compound 'B' is
(1)
(2)
(3)
(4)
123.
Which isomer among the following has highest boiling point?
(1)n-Butylamine
(2)Ethyldimethylamine
(3)tert Butylamine
(4)Diethylamine
124.
The test that distinguishes primary amines from other amines is
(1)Iodoform test
(2)Victor Meyer test
(3)Lucas test
(4)Carbylamine test
125.
A student has been given a compound " x " of molecular formula- C6H7N. ' x ' is sparingly soluble in water. However, on addition of dilute mineral acid, ' x ' becomes soluble in water. ' x ' when treated with CHCl3 and KOH( alc ),’y ' is produced. ' y ' has a specific unpleasant smell. On treatment with benzenesulphonyl chloride, ' x ' gives a compound ' z ' which is soluble in alkali. The number of different " H " atoms present in ' z ' is:-
(1)8
(2)4
(3)5
(4)7
126.
One of the following amides will not undergo Hoffmann bromamide reaction.
(1)CH3CONHCH3
(2)CH3CONH2
(3)CH3CH2CONH2
(4)C6H5CONH2
127.
'A' is
(1)
(2)
(3)
(4)
128.
Which of the following amines undergoes acylation reaction?
(1)Ethyldimethylamine
(2)N-Methylaniline
(3)N,N-Dimethylmethanamine
(4)N,N-Dimethylaniline
129.
The product formed from the following reaction sequence is [NEET 2022] C6H5CN(i) LiAlH4, H2O (ii) NaNO2+HCl (iii) H2O
(1)
(2)
(3)
(4)
130.
What is the IUPAC name of following compound?
(1)1-Methylbut-2-en-1-amine
(2)Pent-3-en-2-amine
(3)Pent-2-en-4-amine
(4)4-Methyl but-2-en-4-amine
131.
The diazonium salt of which of the following compounds will form a coloured dye on reaction with β-Naphthol inNaOH?
(1)
(2)
(3)
(4)
132.
The major product of the following reaction is : (i)Br2/hv(ii)KOH(dil)
(1)
(2)
(3)
(4)
133.
Consider the following reaction, The product X is used:
formed product ’X’ is used as:
(1)Lab test of Phenol
(2)Acid base titration indicator
(3)Food colouring
(4)It can be used as an alternative to detect amino acid in place of ninhydrin
134.
Identify X,Y and Z respectively in the following reaction sequence: Acetic acid(i) NH3, (ii) Δ(iii) C6H5SO2Cl,Pyridine/343KX+Y+Z
(1)C6H5SO3H,CH3NC,HCl
(2)CH3CONH−S(=O)2−C6H5,H2O,HCl
(3)C6H5SO3H,CH3CN,HCl
(4)C6H5SO2Cl,CH3NC,H2O
135.
Identify the structure of Z in the following reaction sequence Phthalic acid+NH3⇌XΔYStrongHeatingZ
(1)
(2)
(3)
(4)
136.
Carbylamine test is used to detect the presence of primary amino group in an organic compound. Which of thefollowing compound is formed when this test is performed with aniline ?
(1)
(2)
(3)
(4)
137.
The order of boiling points of the following compounds is 1.(CH3)3N 2.CH3CH2CH2NH2 3.CH3CH2NHCH3
(1)1>3>2
(2)3>1>2
(3)2>1>3
(4)2>3>1
138.
Hoffmann bromomide degradation of benzamide gives productA, which upon heating with CHCl3and NaOH gives product B. The structures of A and B are:
(1)
(2)
(3)
(4)
139.
Coupling of benzene diazonium chloride with 1-napthol in alkaline medium will give :
(1)
(2)
(3)
(4)
140.
Which among the following is the strongest Bronsted base ?
(1)(CH3CH2)3N¨
(2)(CH3CH2)2N¨H
(3)
(4)
141.
In the following reaction, the product (A) is
(1)
(2)
(3)
(4)
142.
The major product obtained in the following reaction is : (i)CHCl3/KOH(ii)Pd/C/H2
(1)
(2)
(3)
(4)
143.
The reaction of with bromine and gives RNH2 as the end product. Which one of the following is the intermediate product formed in this reaction ?
(1)R−C(=O)−NH−Br
(2)R-NH-Br
(3)R-N=C=O
(4)R−C(=O)−NBr2
144.
Which of the following amines can be prepared by Gabriel phthalimide reaction ?
(1)n- butylamine
(2)trimethylamine
(3)t- butylamine
(4)neo-pentylamine
145.
For reaction The correct order of set of reagents for the above conversion is:
(1)Br2∣FeBr3,H2O(Δ),NaOH
(2)H2SO4,Ac2O,Br2,H2O(Δ),NaOH
(3)Ac2O,Br2,H2O(Δ),NaOH
(4)Ac2O,H2SO4,Br2,NaOH
146.
(1)C>A>B
(2)B>C>A
(3)A>C>B
(4)C>B>A
147.
The Hinsberg reagent is :
(1)
(2)
(3)
(4)
148.
Given below are two statements : one is labelled as Assertion (a) and the other is labelled as Reason(R). Assertion (a) : Experimental reaction of CH3C1 with aniline and anhydrous A1C13 does not give o and p-methylaniline. Reason (R) : The -NH2 group of aniline becomes deactivating because of salt formation with anhydrous A1C13 and hence yields m-methyl aniline as the product. choose the most appropriate answer from the options given below:
(1)Both (a) and (R) are true and (R) is the correct explanation of (a).
(2)Both (a) and (R) are true but (R) is not the correct explanation of (a).
(3)(a) is true, but (R) is false.
(4)(a) is false, but (R) is true.
149.
Phthalimide is made to undergo following sequence of reactions.
Total number of π bonds present in product ' P ' is/are_____
150.
The number of nitrogen atoms in a semicarbazone molecule of acetone is ___