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Set 7 of 10 · Questions 181-210 of 291

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JEE Main Chemistry · Amines · Set 7 (Q181-210)

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  1. 181.
    Hydrolysis of which compound will give carbolic acid ?
    1. (1)Cumene
    2. (2)Benzenediazonium chloride
    3. (3)Benzal chloride
    4. (4)Ethylene glycol ketal
  2. 182.
    The major product of the following synthetic sequence is
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  3. 183.
    A primary aliphatic amine on reaction with nitrous acid in cold (273 K) and there after raising temperature of reaction mixture to room temperature (298 K). Gives a/an
    1. (1)nitrile
    2. (2)alcohol
    3. (3)diazonium salt
    4. (4)secondary amine
  4. 184.
    Identify in the following sequence of reactions.
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  5. 185.
    An organic compound on reduction gives compound , which on reaction with trichloro methane and caustic potash forms . The compound ' ' on catalytic reduction gives -methyl benzenamine, the compound ' ' is
    1. (1)nitrobenzene
    2. (2)nitromethane
    3. (3)methanamine
    4. (4)benzenamine.
  6. 186.
    Which among the following represent reagent 'A'?
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  7. 187.
    Which one of the following compounds will liberate, when treated with ?
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  8. 188.
    An organic compound ' ' having molecular formula reacts with -toluene sulphonyl chloride to form a compound ' ' that is soluble in aqueous . Compound ' ' is optically active and reacts with acetyl chloride to form compound ' '. Identify the compound ' '.
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  9. 189.
    The conversion of propan-1-ol to n-butylamine involves the sequential addition of reagents. The correct sequential order of reagents is.
    1. (1)(i) (ii) KCN (iii) /Ni,Na(Hg)/OH
    2. (2)(i) HC1 (ii) /Ni, Na(Hg)/OH
    3. (3)(i) (ii) KCN (iii)
    4. (4)(i) HC1 (ii)
  10. 190.
    Identify the product ' ' in the following sequence of reactions.
    1. (1)Methyl cyanide
    2. (2)Ethylamine
    3. (3)Methylamine
    4. (4)Ethyl cyanide
  11. 191.
    Yellow dye can be prepared by a coupling reaction of benzene diazonium chloride in acidic medium with . Identify from the following.
    1. (1)Aniline
    2. (2)Phenol
    3. (3)Cumene
    4. (4)Benzene
  12. 192.
    Consider the above reaction, the product A and product B respectively are
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  13. 193.
    Which of the following reactions the used to prepare aryl fluorides from diaronium ats and fleoroboric acid?
    1. (1)Sandmeyer reaction
    2. (2)Baly Schemann reaction
    3. (3)Gattermann reaction
    4. (4)Swarts reaction
  14. 194.
    In the following sequence of reaction identify the major product B
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  15. 195.
    The reaction of benzenediazonium chloride with aniline yields yellow dye. The name of the yellow dye is
    1. (1)p-hydroxyazobenzene
    2. (2)-aminoazobenzene
    3. (3)p-nitroazobenzenc
    4. (4)o-nitroazobenzene.
  16. 196.
    Compound A is converted to B on reaction with and . The compound B is toxic and can be decomposed by C. A, B and C respectively are :
    1. (1)primary amine, nitrile compound, conc. HCl
    2. (2)secondary amine, isonitrile compound, conc. NaOH
    3. (3)primary amine, isonitrile compound, conc. HCl
    4. (4)secondary amine, nitrile compound, conc. NaOH
  17. 197.
    Consider the above reaction, compound B is :
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  18. 198.

    What is ' ' in the above sequence of reactions?
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  19. 199.
    Which of the following is NOT a correct method of the preparation of benzylamine from cyanobenzene ?
    1. (1)
    2. (2)(i) (ii)
    3. (3)(i) (gas) (ii)
    4. (4)(i) (ii)
  20. 200.
    Consider the above reaction, the Product "P" is :
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  21. 201.
    Acetic acid on heating with forms . When reacts with followed by hydrolysis gives . When is heated with chloroform in medium gives . What are and respectively?
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  22. 202.
    The final product 'C' is the following series series of reactions
    is
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  23. 203.
    Identify the reagents used in the conversion of 3-methylaniline to 3-nitrotoluene.
    X Y Z
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  24. 204.
    Identify the product in the following reaction.
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  25. 205.
    Consider following reaction, where(A) The change in the functional group and(B) The corresponding change in the hybridization from starting to the final product A and B are

    1. (1)-CN to -CH2-OH sp2 to
    2. (2)-CN to to
    3. (3)-CN to to
    4. (4)-CN to to
  26. 206.
    The major products A and B for the following reactions are, respectively:
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  27. 207.
    The sequence of reagents which convert p-methyl aniline to p-methyl benzoic acid are
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  28. 208.
    The major product formed in the reaction given below will be :
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  29. 209.
    Identify the amine formed when ethyltrimethyl ammonium iodide is treated with silver hydroxide and further heated strongly.
    1. (1)
    2. (2)
    3. (3)
    4. (4)
  30. 210.
    A reaction of mole of Benzylamine with bromomethane gave of Benzyl trimethyl ammoniumbromide. The number of moles of bromomethane consumed in this reaction are, when (Round off to the Nearest Integer).(Given : Atomic masses:,