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Mere Teacher · Previous Year Questions
JEE Main Chemistry · General Organic Chemistry · Set 14 (Q391-420)
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391.
In 3,3-dimethylhex-1-en-4-yne, there are sp3, sp2 and sp hybridized carbon atoms respectively.
(1)4,2,2
(2)2,4,2
(3)3,3,2
(4)2,2,4
392.
Which of the following has highly acidic hydrogen?
(1)
(2)
(3)
(4)
393.
The total number of π‐bond electrons in the following structure is
(1)12
(2)16
(3)4
(4)8
394.
The major product of the following reaction is :
(1)CH3CH=C=CH2
(2)CH3CH=CHCH2NH2
(3)CH3CH2C≡CH
(4)CH3CH2CH(NH2)−CH2NH2
395.
The correct IUPAC name of the following compound is:
(1)5-chloro-4-methyl-1-nitrobenzene
(2)2 -chloro- 1 -methyl- 4 -nitrobenzene
(3)3-chloro-4-methyl- 1 -nitrobenzene
(4)2 -methyl-5-nitro-1-chlorobenzene
396.
In the following halogenated organic compounds the one with maximum number of chlorine atoms in its structure is :
(1)Chloral
(2)Gammaxene
(3)Chloropicrin
(4)Freon-12
397.
Which one of the following compounds is non-aromatic ?
(1)
(2)
(3)
(4)
398.
Amongst the following compounds, the optically acitve alkane having lowest molecular mass is
(1)CH3–CH2–CH2–CH3
(2)CH3−CH2−CH(CH3)−CH3
(3)
(4)CH3–CH2–C≡CH
399.
The reaction : (CH3)3C–Br H2O(CH3)3C–OH is an example of –
(1)elimination reaction.
(2)substitution reaction.
(3)free radical reaction.
(4)rearrangement reaction.
400.
The IUPAC name of ethylidene chloride is :-
(1)1-Chloroethene
(2)1-Chloroethyne
(3)1,2-Dichloroethane
(4)1,1-Dichloroethane
401.
Out of the following, the alkene that exhibits optical isomerism is.
(1)3-methyl-2pentene
(2)4-methyl-1-pentene
(3)3-methyl-1-pentene
(4)2-methyl-2-pentene
402.
The correct order of acid character of the following compounds is:
(1)II > III > IV > I
(2)III > II > I > IV
(3)IV > III > II > I
(4)I > II > III > IV
403.
The ascending acidity order of the following H atoms is
(1)C < D < B < A
(2)A < B < C < D
(3)A < B < D < C
(4)D < C < B < A
404.
The correct order of acid strength of the following compounds: (A) Phenol (B) p-Cresol (C) m-Nitrophenol (D) p-Nitrophenol is :
(1)D > C > A > B
(2)B > D > A > C
(3)A > B > D > C
(4)C > B > A > D
405.
How many chiral compounds are possible on monochlorination of 2-methylbutane
(1)8
(2)2
(3)4
(4)6
406.
Arrange the following in decreasing acidic strength.
(1)A>B>C>D
(2)B>A>C>D
(3)D>C>A>B
(4)D > C> B > A
407.
The enolic form of ethyl acetoacetate as below has :
(1)16 sigma bonds and 1 pi- bond
(2)9 sigma bonds and 2 pi- bond
(3)9 sigma bonds and 1 pi- bond
(4)18 sigma bonds and 2 pi- bond
408.
The IUPAC name of the following compound is:
(1)Methyl-6-carboxy-2,5-dimethylhexanoate.
(2)2-Carboxy-5-methoxycarbonylhexane.
(3)6-Methoxycarbonyl-2,5-dimethylhexanoic acid.
(4)Methyl-5-carboxy-2-methylhexanoate.
409.
Which of the following compounds will most readily be dehydrated to give alkene under acidic condition?
(1)4-Hydroxypentan-2-one
(2)3-Hydroxypentan-2-one
(3)1-Pentanol
(4)2-Hydroxycyclopentanone
410.
In SN2 reactions, the correct order of reactivity for the following compounds: CH3Cl, CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is :
Increasing order of stability among the three main conformations (i.e. eclipse, anti, gauche) of 2-fluoroethanol is
(1)eclipse, gauche, anti
(2)gauche, eclipse, anti
(3)eclipse, anti, gauche
(4)anti, gauche, esclipse
412.
CH3 – CHCI – CH2 – CH3 has a chiral centre which one of the following represents its R configuration :
(1)
(2)
(3)
(4)
413.
Which of the following compounds will show the maximum 'enol' content?
(1)CH3COCH2COOC2H5
(2)CH3COCH2COCH3
(3)CH3COCH3
(4)CH3COCH2CONH2
414.
The IUPAC name(s) of the following compound is (are)
(1)4-methylchlorobenzene
(2)4-chlorotoluene
(3)1-chloro-4-methylbenzene
(4)1-methyl-4-chlorobenzene
415.
Which of the following structures are aromatic in nature?
(1)A,B,C and D
(2)Only A and B
(3)Only A and C
(4)Only B,C and D
416.
Among the following the reaction that produce through an electrophilic substitution is :
(1)
(2)
(3)
(4)
417.
While estimating the nitrogen present in an organic compound by Kjeldahl's method, the ammonia evolved from 0.25 g of the compound neutralized 2.5 mL of 2 M H2S04. The percentage of nitrogen present in organic compound is.......
418.
The number of optical isomers in following compound is:_______
419.
The total number of monobromo derivatives formed by the alkanes with molecular formula C5H12 is (excluding stereo isomers)_____
420.
The total number of basic groups in the following form of lysine is :