331.Product 'A' of following sequence of reactions is Ethylbenzene 'A'(Major product)- (1)
- (2)
- (3)
- (4)
332.In the following reaction, Compound (A) and (B) respectively are- (1)Nitrobenzene and fluorobenzen
- (2)Phenol and benzene
- (3)Benzene diazonium chloride and fluorobenzene
- (4)Nitrobenzene and chlorobenzene
333.The electrolytic reduction of nitrobenzene in strongly acidic medium produces :- (1)Anoxybenzene
- (2)Azobenzene
- (3)Aniline
- (4)p-Aminophenol
334.Predict the major product of the following reaction sequence:-- (1)
- (2)
- (3)
- (4)
335.Which among the following pairs of the structures will give different products on ozonolysis? (Consider the double bonds in the structures are rigid and not delocalized.)- (1)
- (2)
- (3)
- (4)
336.Of the five isomeric hexanes, the isomer which can give two monochlorinated compound is- (1)n - hexane
- (2)2,3 - dimethylbutane
- (3)2,2 - dimethylbutane
- (4)2 - methylpentane
337.In the reaction the intermediate (s) is (are)- (1)
- (2)
- (3)
- (4)
338.The major product (A) formed in the reaction given below is :- (1)
- (2)
- (3)
- (4)
339.Choose the correct set of reagents for the following conversion trans (Ph-CH=CH-CH3) →cis (Ph-CH=CH-CH3)- (1)Br2, alcKOH, NaNH2,Na(LiqNH3)
- (2)Br2, alcKOH,NaNH2,H2 Lindlar Catalyst
- (3)Br2, aqKOH,NaNH2,H2Lindlar Catalyst
- (4)Br2,aqKOH,NaNH2,Na(LiqNH3)
340.In the chemical reactions given above A and B respectively are:- (1)H3PO2and CH3CH2Cl
- (2)CH3CH2OHand H3PO2
- (3)H3PO2and CH3CH2OH
- (4)CH3CH2Cland H3PO2
341.2‐Bromopentane is heated with potassium ethoxide in ethanol. The major product obtained is- (1)trans‐2‐pentene
- (2)1‐pentene
- (3)2‐ethoxy pentane
- (4)2‐cis‐pentene.
342.In the following reaction
The major product is- (1)CH3−C(CH3)(CH3)−CH(CH3)−CH3
- (2)CH2(OH)−C(CH3)(CH3)−CH2−CH3
- (3)CH3−C(CH3)(CH3)−CH(OH)−CH3
- (4)CH3−C(CH3)(CH3)−CH2−CH2(OH)
343.Identify ' X ' in the following reaction.- (1)
- (2)
- (3)
- (4)
344.In which of the following compounds, the C–Cl bond ionisation shall give most stable carbonium ion ?- (1)C(H3C)(H3C)(CH3)−Cl
- (2)
- (3)O2NH2C−C(H)(H)−Cl
- (4)C(H3C)(H3C)(H)−Cl
345.The major product formed in the following reaction is CH3CH=CHCH(CH3)2⟶HBr- (1)Br(CH2)3CH(CH3)2
- (2)CH3CH(Br)CH2CH(CH3)2
- (3)CH3CH2CH(Br)CH(CH3)2
- (4)CH3CH2CH2C(Br)(CH3)2
346.Which of the following reactions is appropriate for converting acetamide to methanamine ?- (1)Carbylamine reaction
- (2)Hoffmann hypobromamide reaction
- (3)Stephens reaction
- (4)Gabriels phthalimide synthesis
347.In the reaction with HC1, an alkene reacts in accordance with the Markovnikov’s rule to give a product l‐chloro‐l‐methylcyclohexane. The possible alkene is- (1)
- (2)
- (3)(A) and (B)
- (4)
348.In the reaction the compound (A) is known as : C6H5CHO + C6H5NH2 C6H5N = CHC6H5 + H2O (A)- (1)Aldol
- (2)Schiff base
- (3)Schiff reagent
- (4)Benedict's reagent
349.What is the major product formed by HI on reaction with ?- (1)CH3−C(CH3)(CH3)−CH(I)−CH3
- (2)CH3−CH(CH3)−CH(I)−CH2−CH3
- (3)CH3−C(CH3)(I)−CH(CH3)−CH3
- (4)CH3−C(CH3)(CH3)−CH(H)−CH2I
350.The final major product of the following reaction is- (1)
- (2)
- (3)
- (4)
351.What will be the major product of following sequence of reactions?- (1)
- (2)
- (3)
- (4)
352.In the following reaction sequence,
the major product B is :- (1)
- (2)
- (3)
- (4)
353.Phenol on treatment with CO2 in the presence of NaOH followed by acidification produces compound X as the major product. X on treatment with (CH3CO)2O in the presence of catalytic amount of H2SO4 produces :- (1)
- (2)
- (3)
- (4)
354.consider the above reaction, and choose the correct statement:- (1)The reaction is not possible in acidic medium
- (2)Both compounds A and B are formed equally
- (3)Compound A will be the major product
- (4)Compound B will be the major product
355.A given nitrogen-containing aromatic compound A reacts with Sn/HCl, followed by HNO2 to give an unstable compound B. B, on treatment with phenol, forms a beautiful coloured compound C with the molecular formula C12H10N2O. The structure of compound A is :- (1)
- (2)
- (3)
- (4)
356.Nitrobenzene on reaction with conc. HNO3 /H2SO4 at 80 – 100ºC forms which one of the following products ?- (1)1, 3– Dinitrobenzene
- (2)1, 4– Dinitrobenzene
- (3)1, 2, 4– Trinitobenzene
- (4)1, 2– Dinitrobenzene
357.The correct sequence of correct reagents for the following transformation is :-- (1)(i) Fe, HCl (ii) Cl2,HCl, (iii) NaNO2,HCl,00C (iv)H2O/H+
- (2)(i) Fe, HCl (ii)NaNO2,HCl,00C (iii)H2O/H+ (iv)Cl2,FeCl3
- (3)(i)Cl2,FeCl3 (ii) Fe, HCl (iii)NaNO2,HCl,00C (iv)H2O/H+
- (4)(i)Cl2,FeCl3 (ii) NaNO2,HCl,00C(iii) Fe, HCl (iv)H2O/H+
358.Which of the compound with molecular formula C5H10 yields acetone on ozonolysis?- (1)3‐Methyl −1‐butene
- (2)Cyclopentane
- (3)2‐Methyl‐l‐butene
- (4)2‐Methyl‐2‐butene
359.An alkene on ozonolysis gives methanal as one of the product. Its structure is :- (1)
- (2)
- (3)
- (4)
360.Total number of isomeric compounds (including stereoisomers) formed by monochlorination of 2 methylbutane is_______
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