In the print window choose “Save as PDF”. The file prints without a web address or date line.
Mere Teacher · Previous Year Questions
JEE Main Chemistry · Hydrocarbons · Set 15 (Q421-450)
Scan or visit mereteacher.com for free PYQ practice, timed CBT tests, step-by-step solutions and BroBot AI. Answers and solutions are free with a sign-up.
421.
The major product obtained in the following conversion is: Br2(1eq.)MeOH
(1)
(2)
(3)
(4)
422.
What is the number of moles of ethane obtained from 2n moles of bromomethane using 2n moles of sodium atoms in dry ether medium?
(1)4n
(2)3n
(3)2n
(4)n
423.
The most suitable reagent for the following conversion, is
(1)Hg2+/H+,H2O
(2)Na/liquid NH3
(3)H2,Pd/C, quinoline
(4)Zn/HC1
424.
In the given reactions identify the reagent A and reagent B
(1)A−CrO3B−CrO3
(2)A−CrO3 B - CrO2Cl2
(3)A−CrO2Cl2 B - CrO2Cl2
(4)A−CrO2Cl2B−CrO3
425.
The treatment of benzene with isobutene in the presence of sulphuric acid gives :
(1)isobutyl benzene
(2)tert-butyl benzene
(3)n-butyl benzene
(4)no reaction
426.
An alkene X on ozonolysis gives a mixture of Propan-2one and methanal. What is X?
(1)Propene
(2)2-Methylpropene
(3)2-Methylbut-1-ene
(4)2-Methylbut-2-ene
427.
In the following reaction, H3C−C≡CHred hot iron tube873KA,
the number of sigma(σ) bonds present in the product A, is
(1)2l
(2)9
(3)24
(4)18
428.
Phenol is heated with a solution of mixture of KBr and KBrO3. The major product obtained in the above reaction is :
(1)2-Bromophenol
(2)3-Bromophenol
(3)4-Bromophenol
(4)2, 4, 6 -Tribromophenol
429.
The major product of the following reaction is: (i)KOHalc.(ii)NaNH2inliq.NH3
(1)CH3CH=C=CH2
(2)CH3CH2CH(NH2)−CH2NH2
(3)CH3CH=CHCH2NH2
(4)CH3CH2C≡CH
430.
The reaction of chloroform with alcoholic KOH and p-toluidine forms :
(1)
(2)
(3)
(4)
431.
In the following reaction sequence the major products A and B are:
(1)
(2)
(3)
(4)
432.
Methane can be converted into ethane by the reactions
(1)chlorination followed by the reaction with alcoholic KOH
(2)chlorination followed by the reaction with aqueous KOH
(3)chlorination followed by Wurtz reaction
(4)chlorination followed by decarboxylation.
433.
An organic compound 'A'C4H8 on treatment with KMnO4/H+yields compound 'B' C3H6O.Compound 'A' also yields compound 'B' an ozonolysis. Compound 'A' is :
(1)2-Methylpropene
(2)1-Methylcyclopropane
(3)But-2-ene
(4)Cyclobutane
434.
When CH3CH2CHCl2 is treated with NaNH2, the product formed is
(1)CH3−CH=CH2
(2)CH3−C≡CH
(3)CH3CH2CH(NH2)2
(4)CH3CH2CH(Cl)NH2
435.
The angle strain in cyclobutane is
(1)19∘22’
(2)9∘44’
(3)24∘44’
(4)29∘16’
436.
Picric acid is
(1)
(2)
(3)
(4)
437.
The homologue of ethyne is :
(1)C2H2
(2)C2H6
(3)C3H8
(4)C3H4
438.
Picric acid is
(1)
(2)
(3)
(4)
439.
(i)Bra,hvA→(iii)O3(ii)KOH(alc.) (iv)(CH3)2S(v)NaOH(aq)+Δ In the following reaction A is:
(1)
(2)
(3)
(4)
440.
[P] on treatment with Br2/FeBr3 in CCl4 produced a single isomer C8H7O2 while heating [P] with sodalime gave toluene. The compound [P] is
(1)
(2)
(3)
(4)
441.
A solution of m-chloroaniline, m-chlorophenol and m-chlorobenzoic acid in ethyl acetate was extracted initially with a saturated solution of NaHCO3 to give fraction A. The left over organic phase was extracted with dilute NaOH solution to give fraction B. The final organic layer was labelled as fraction C. Fraction A,B and C, contain respectively :
(1)m-chlorobenzoic acid, m-chlorophenol and m-chloroaniline
(2)m-chlorophenol, m-chlorobenzoic acid and m-chloroaniline
(3)m-chloroaniline,m-chlorobenzoic acid and m-chlorophenol
(4)m-chlorobenzoic acid, m-chloroaniline and m-chlorophenol
442.
Major product P of above reaction, is :
(1)
(2)
(3)
(4)
443.
Predict the product,
(1)
(2)
(3)
(4)
444.
In the reaction H−C≡CH(i) NaNH2 / liQ. NH3(ii) CH3CH2BrX(i) NaNH2 / liQ. NH3(ii) CH3CH2BrY
(1)X=2‐Butyne, Y=2‐Hexyne
(2)X=1‐Butyne, Y=2‐Hexyne
(3)X=1‐Butyne, Y=3‐Hexyne
(4)X=2‐Butyne, Y=3‐Hexyne.
445.
Match List - I with List - II. List-I (Reaction)(A)(B)ArN2+X−→CuHClArCl+N2↑+CuX(C)C2H5BrNaI→DryAcetoneC2H5I+NaBr(D)CH3C(OH)(CH3)CH3→HClZnCl2CH3C(Cl)(CH3))CH3List - II (Name of reaction)(I) Lucas reaction(II) Finkelstein reaction(III) Fittig reaction(IV) Gatterman reaction Choose the correct answer from the options given below: