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301.
n-Propanol on treatment with concentrated HBr gives P. The product P on reaction with KCN gave the product Q. The product Q on heating with aqueous acidic solution, furnished the product R. The product ' R ' is
(1)Propanoic acid
(2)Propanamide
(3)Butanoic acid
(4)Butanamide
302.
The structure of intermediate A in the following reaction is
(1)
(2)
(3)
(4)
303.
Major product in the following reaction sequence is
(1)
(2)
(3)
(4)
304.
CH3 – CH2C ≡ N X CH2CH2CHO The compound X is :
(1)SnCl2 / HCl / H2O,
(2)H2 / Pd – BaSO4
(3)LiAlH4 / ether
(4)NaBH4 / ether H3O+
305.
Among the following, the products formed by the reaction of anisole with HI are
(1)benzene + methanol
(2)phenol + methane
(3)phenol + iodomethane
(4)sodium phenate + methanol.
306.
(C7H5O2)2hν[x]+2C∙6H5+2CO2 Consider the above reaction and identify the intermediate 'X'
(1)C6H5−C(=O)⊕
(2)C6H5−C(=O)−O⊖
(3)C6H5−C(=O)−..O..
(4)C6H5−C(=O)−..O..⋅
307.
Which of the following is secondary benzylic alcohol?
(1)
(2)
(3)
(4)
308.
Identify the major product (Y) from the following reaction
(1)
(2)
(3)
(4)
309.
The best reagent to convert pent-3-en-2-ol into pent-3-ene-2-one is
(1)Pyridinium chloro-chromate
(2)Chromic anhydride in glacial acetic acid
(3)Acidic dichromate
(4)Acidic permanganate
310.
Reaction of phenol with which of the following reagents form picric acid?
(1)Conc. H2SO4
(2)dil. H2SO4
(3)Conc. HNO3
(4)dil. HNO3
311.
Salicylaldehyde is synthesized from phenol, when reacted with
(1), NaOH
(2)CO2,NaOH
(3)CCl4,NaOH
(4)HCCl3,NaOH
312.
In the following reaction,
the compound Z is
(1)benzoic acid
(2)benzaldehyde
(3)acetophenone
(4)benzene
313.
Which one of the following, with HBr will give a phenol?
(1)
(2)
(3)
(4)
314.
Which one of the following is reduced with zinc and hydrochloric acid to give the corresponding hydrocarbon?
(1)Ethyl acetate
(2)Butan-2-one
(3)Acetamide
(4)Acetic acid
315.
In Reimer - Tiemann reaction, phenol is converted into salicylaldehyde through an intermediate. The structure of intermediate is
(1)
(2)
(3)
(4)
316.
The reagent used to distinguish between acetaldehyde and benzaldehyde is
(1)Tollens' reagent
(2)Fehling's solution
(3)2,4-dinitrophenylhydrazine
(4)semicarbazide.
317.
The test to differentiate between pentan-2one and pentan-3-one is
(1)Fehlings test
(2)iodoform test
(3)Baeyer's test
(4)Benedict's test.
318.
PH2/Pd–BaSO4Q(i) conc. NaOH(ii) dil. HClR+S R and S form benzyl benzoate when treated with each other. Hence, p is
(1)C6H5CHO
(2)C6H5CH2OH
(3)C6H5COCl
(4)C6H5COOH
319.
The major aromatic product of the following reaction sequence is
(1)
(2)
(3)
(4)
320.
In the reaction : C6H5CN(i) SnCl2+HCl(ii) H3O+Xconc. KOHY+Z,
Formation of X, formation of Y and Z are known by
(1)Rosenmund reduction, Cannizzaro reaction
(2)Clemmensen reduction, Sandmeyer reaction
(3)Wolff-Kishner reduction, Wurtz reaction
(4)Stephen reaction, Cannizzaro reaction.
321.
The major product (P) formed in the below reaction is
(1)
(2)
(3)
(4)
322.
An organic compound gives dark green colouration with ferric chloride. On treatment with CHCl3and KOH, followed by acidification gives compound B. Compound B can also be obtained from compound on reaction with pyridiniumchlorochromate(PCC). Identify A, B and C.
(1)
(2)
(3)
(4)
323.
When formic acid is heated with concentrated H2SO4, the gas evolved is
(1)only CO2
(2)only CO
(3)a mixture of CO and CO2
(4)a mixture of SO2 and CO2.
324.
Identify (A) in the following reaction sequence: Gives Positive lodoform test (A)→(ii)H+,H2O(3)Conc.H2SO4/Δ(i)CH3MgBr(B)⟶O3/Zn,H2O
(1)
(2)
(3)
(4)
325.
Identify ∘C ' in the following:
(1)Water
(2)Ethanol
(3)Propanone
(4)Cumene hydroperoxide
326.
In the following sequence of reactions, CH3Br→KCNA→H3O+B→LiAlH4C The end product C is
(1)methane
(2)ethyl alcohol
(3)acetone
(4)acetaldehyde.
327.
The appropriate reagent for the following transformation is
(1)Zn−Hg/HCl
(2)H2N−NH2,KOH/ ethylene glycol
(3)Ni/H2
(4)NaBH4
328.
The major product in the following conversion is :
(1)
(2)
(3)
(4)
329.
The product "A" in the above reaction is:
(1)
(2)
(3)
(4)
330.
When CH2=CH−O−CH2−CH3 reacts with one mole of HI, one of the products formed is