121.Compound A,C8H10O, is found to react with NaOI (produced by reacting Y with NaOH) and yields a yellow precipitate with characteristic smell. A and Y are respectively. [NEET 2018]- (1)
- (2)
- (3)
- (4)
122.Suitable reaction condition for preparation of Methyl phenyl ether is- (1)PhO−Na+,MeOH
- (2)Benzene, MeBr
- (3)Ph – Br, MeO−Na+
- (4)PhO−Na+, MeBr
123.Product [X] formed in the above reaction is:- (1)H3C−CH2−C(H)(OH)−CH3
- (2)H3C−CH=CH−CH3
- (3)H3C−CH2−CH(D)−CH3
- (4)H3C−CH2−CH=CH2
124.The carbonyl compound that does not undergo aldol condensation is- (1)dichloroacetaldehyde
- (2)trichloroacetaldehyde
- (3)acetaldehyde
- (4)acetone.
125.What is the product obtained in Reimer-Tiemann reaction?- (1)Salicylaldehyde
- (2)2, 4, 6-trinitrophenol
- (3)Salicylic acid
- (4)Aniline
126.Identify the major product of the following reaction.- (1)
- (2)
- (3)
- (4)
127.Given are cyclohexanol (I), acetic acid (II), 2,4,6‐trinitrophenol (III) and phenol (IV). In these the order of decreasing acidic character will be- (1)III>II>IV>I
- (2)II>III>I>IV
- (3)II>III>IV>I
- (4)III>IV>II>I
128.The bond angle of bond in methoxy methane is- (1)111.7c
- (2)109∘
- (3)108.9∘
- (4)180∘
129.Reaction of which among the following ethers with HI in cold leads to the formation of methyl alcohol?- (1)Ethyl methyl ether
- (2)Methyl propyl ether
- (3)Isopropyl methyl ether
- (4)tert-Butyl methyl ether
130.The given reaction can occur in the presence of : (A) Bromine water (B) Br2inCS2,273K (C)Br2/FeBr3 (D)Br2 inCHCl3,273K
Choose the correct answer from the options given below:- (1)(B) and (D) only
- (2)(A) and (C) only
- (3)(B), (C) and (D) only
- (4)(A), (B) and (D) only
131.Which of the following gives an aldehyde on dry distillation?- (1)Calcium formate + calcium acetate
- (2)Calcium acetate + calcium benzoate
- (3)Calcium acetate
- (4)Calcium benzoate
132.The order of reactivity of the following compounds towards the esterification with acetic acid is- (1)I > II > III > IV
- (2)IV > III > II > I
- (3)I > IV > II > III
- (4)I > IV > III > II
133.Among the following the appropriate reactants for the preparation of 1 - ethyl cyclohexanol are- (1)
- (2)
- (3)
- (4)
134.Identify the products (X,Y) and reaction mechanism (Z) of the following reaction?- (1)
- (2)
- (3)
- (4)
135.Which of the following compounds will provide a tertiary alcohol on reaction with excess of CH3MgBrfollowed by hydrolysis?- (1)
- (2)
- (3)
- (4)
136.Phenol can be distinguished from ethanol by the reagent- (1)bromine water
- (2)sodium metal
- (3)iron metal
- (4)chlorine water.
137.Which of the following is a secondary allylic alcohol?- (1)H2C=CH−CH2−OH
- (2)CH3−CH=CH−CH2−OH
- (3)H2C=CH−CHCH3−OH
- (4)CH2=CH−C(CH3)2−OH
138.Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Treatment of bromine water with propene yields 1- bromopropan -2-ol. Reason (R): Attack of water on bromonium ion follows Markovnikov rule and results in 1- bromopropan -2-ol. choose the answer from the options given below :- (1)Both (A) and (R) are true but (R) is NOT the correct explanation of (A).
- (2)(A) is false but (R) is true.
- (3)Both (A) and (R) are true and (R) is the correct explanation of (A).
- (4)(A) is true but (R) is false.
139.Anisole can be prepared by the action of methyl iodide on sodium phenate. The reaction is called- (1)Fittig reaction
- (2)Etard reaction
- (3)Wurtz reaction
- (4)Williamson reaction.
140.The products formed during the following reaction are- (1)CH3OH+CH3−C(CH3)2−I
- (2)CH4+H3C−C(CH3)2−OI
- (3)CH3I+CH3−C(CH3)2−OH
- (4)CH3OI+H3C−C(CH3)2−H
141.The acid strength of active methylene group in (i) CH3COCH2COOC2H5 (ii) CH3COCH2COCH3 (iii) C2H5OOCCH2COOC2H5 decreases as- (1)i > iii > ii
- (2)i > ii > iii
- (3)ii > i > iii
- (4)iii > i > ii
142.The compound A on treatment with Na gives B, and with PCl5 gives C. B and C react together to give diethyl ether. A,B and C are in the order [NEET 2018]- (1)C2H5Cl,C2H6,C2H5OH
- (2)C2H5OH,C2H5Cl,C2H5ONa
- (3)C2H5OH,C2H6,C2H5Cl
- (4)C2H5OH,C2H5ONa,C2H5Cl
143.The correct order of boiling points of following compounds is- (1)I > II > III
- (2)II > I > III
- (3)III > II > I
- (4)II > III > I
144.The reagents A,B and C respectively are- (1)H2/Pd,PCC,NaBH4
- (2)NaBH4, alk. KMnO4,H2/Pd
- (3)NaBH4,PCC,H2/Pd
- (4)H2/Pd, alk. KMnO4,NaBH4
145.The major products C and D formed in the following reactions respectively are [NEET 2019] H3C−CH2−CH2−OC(CH3)3ExcessHI∆C+D- (1)H3C−CH2−CH2−I and I−C(CH3)3
- (2)H3C−CH2−CH2−OH and I−C(CH3)3
- (3)H3C−CH2−CH2−I and HO−C(CH3)3
- (4)H3C−CH2−CH2−OH and HO−C(CH3)3
146.The heating of phenyl-methyl ethers with HI produces. [NEET 2017]- (1)ethyl chlorides
- (2)iodobenzene
- (3)phenol
- (4)benzene
147.Which one of the following compounds is resistant to nucleophilic attack by hydroxyl ions?- (1)Diethyl ether
- (2)Acetonitrile
- (3)Acetamide
- (4)Methyl acetate
148.An organic compound (A) (molecular formula C6H12O2 ) was hydrolysed with dil. H2SO4 to give a carboxylic acid (B) and an alcohol (C). ’C gives white turbidity immediately when treated with anhydrouZnCl2 and conc. HCl. The organic compound (A) is- (1)
- (2)
- (3)
- (4)
149.The major product of the following reaction is- (1)CH3CH2CH3
- (2)CH3CH=CH2
- (3)CH3C≡CH
- (4)CH3COCH3
150.Reaction of phenol with chloroform in the presence of dilute sodium hydroxide finally introduces, which one of the following functional group?- (1)−CH2Cl
- (2)-COOH
- (3)−CHCl2
- (4)-CHO
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