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Mere Teacher · Previous Year Questions
NEET Chemistry · Amines · Set 5 (Q121-150)
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121.
What is the IUPAC name of following compound?
(1)1-Methylbut-2-en-1-amine
(2)Pent-3-en-2-amine
(3)Pent-2-en-4-amine
(4)4-Methyl but-2-en-4-amine
122.
The diazonium salt of which of the following compounds will form a coloured dye on reaction with β-Naphthol inNaOH?
(1)
(2)
(3)
(4)
123.
The major product of the following reaction is : (i)Br2/hv(ii)KOH(dil)
(1)
(2)
(3)
(4)
124.
Consider the following reaction, The product X is used:
formed product ’X’ is used as:
(1)Lab test of Phenol
(2)Acid base titration indicator
(3)Food colouring
(4)It can be used as an alternative to detect amino acid in place of ninhydrin
125.
Identify X,Y and Z respectively in the following reaction sequence: Acetic acid(i) NH3, (ii) Δ(iii) C6H5SO2Cl,Pyridine/343KX+Y+Z
(1)C6H5SO3H,CH3NC,HCl
(2)CH3CONH−S(=O)2−C6H5,H2O,HCl
(3)C6H5SO3H,CH3CN,HCl
(4)C6H5SO2Cl,CH3NC,H2O
126.
Identify the structure of Z in the following reaction sequence Phthalic acid+NH3⇌XΔYStrongHeatingZ
(1)
(2)
(3)
(4)
127.
Carbylamine test is used to detect the presence of primary amino group in an organic compound. Which of thefollowing compound is formed when this test is performed with aniline ?
(1)
(2)
(3)
(4)
128.
The order of boiling points of the following compounds is 1.(CH3)3N 2.CH3CH2CH2NH2 3.CH3CH2NHCH3
(1)1>3>2
(2)3>1>2
(3)2>1>3
(4)2>3>1
129.
Hoffmann bromomide degradation of benzamide gives productA, which upon heating with CHCl3and NaOH gives product B. The structures of A and B are:
(1)
(2)
(3)
(4)
130.
Coupling of benzene diazonium chloride with 1-napthol in alkaline medium will give :
(1)
(2)
(3)
(4)
131.
Which among the following is the strongest Bronsted base ?
(1)(CH3CH2)3N¨
(2)(CH3CH2)2N¨H
(3)
(4)
132.
In the following reaction, the product (A) is
(1)
(2)
(3)
(4)
133.
The major product obtained in the following reaction is : (i)CHCl3/KOH(ii)Pd/C/H2
(1)
(2)
(3)
(4)
134.
The reaction of with bromine and gives RNH2 as the end product. Which one of the following is the intermediate product formed in this reaction ?
(1)R−C(=O)−NH−Br
(2)R-NH-Br
(3)R-N=C=O
(4)R−C(=O)−NBr2
135.
Which of the following amines can be prepared by Gabriel phthalimide reaction ?
(1)n- butylamine
(2)trimethylamine
(3)t- butylamine
(4)neo-pentylamine
136.
For reaction The correct order of set of reagents for the above conversion is:
(1)Br2∣FeBr3,H2O(Δ),NaOH
(2)H2SO4,Ac2O,Br2,H2O(Δ),NaOH
(3)Ac2O,Br2,H2O(Δ),NaOH
(4)Ac2O,H2SO4,Br2,NaOH
137.
(1)C>A>B
(2)B>C>A
(3)A>C>B
(4)C>B>A
138.
The Hinsberg reagent is :
(1)
(2)
(3)
(4)
139.
Given below are two statements : one is labelled as Assertion (a) and the other is labelled as Reason(R). Assertion (a) : Experimental reaction of CH3C1 with aniline and anhydrous A1C13 does not give o and p-methylaniline. Reason (R) : The -NH2 group of aniline becomes deactivating because of salt formation with anhydrous A1C13 and hence yields m-methyl aniline as the product. choose the most appropriate answer from the options given below:
(1)Both (a) and (R) are true and (R) is the correct explanation of (a).
(2)Both (a) and (R) are true but (R) is not the correct explanation of (a).
(3)(a) is true, but (R) is false.
(4)(a) is false, but (R) is true.
140.
Which of the following is more basic than aniline?
(1)Diphenylamine
(2)Triphenylamine
(3)p-Nitroaniline
(4)Benzylamine
141.
The conversion of m-nitrophenol to resorcinol involves respectively
(1)hydrolysis, diazotization and reduction
(2)diazotization, reduction and hydrolysis
(3)hydrolysis, reduction and diazotization
(4)reduction, diazotization and hydrolysis.
142.
Which one of the following forms propane nitrile as the major product?
(1)Ethyl bromide + alcoholic KCN
(2)Propyl bromide + alcoholic KCN
(3)Propyl bromide + alcoholic AgCN
(4)Ethyl bromide + alcoholic AgCN
143.
Benzylamine is a stronger base than aniline because
(1)the lone pair of electrons on the nitrogen atom in benzylamine is delocalised
(2)the lone pair of electrons on the nitrogen atom in aniline is delocalised
(3)the lone pait of electrons on the nitrogen atom in aniline is not involved in resonance
(4)benzylamine has a higher molecular mass than aniline.
144.
CH3CH2Br→aq.KOHΔA→KMnO4/H+ΔB→NH3ΔC→Br2alkaliD D is
(1)CH3Br
(2)CH3CONH2
(3)CH3NH2
(4)CHBr3
145.
An aromatic compound A(C7H9N) on reacting with NaNO2/HCl at 0∘C forms benzyl alcohol and nitrogen gas. The number of isomers possible for the compound A is
(1)5
(2)7
(3)3
(4)6
146.
In the following reactions, P,Q and R are
(1)
(2)
(3)
(4)
147.
In which of the following, reagent and product are correctly matched with respect to benzene diazonium chloride as reactant?
(1)Cu2O;C6H5Br
(2)HI;C6H5I
(3)NaNO2;C6H5NO
(4)CH3CH2OH;C6H6
148.
The product A formed in the following reaction is:
(1)
(2)
(3)
(4)
149.
The major product (A) formed in the following reaction sequence is
(1)
(2)
(3)
(4)
150.
Given below are two statements, one is labelled as Assertion (A) and other is labelled as Reason (R). Assertion (R) : Gabriel phthal imide synthesis cannot be used to prepare aromatic primary amines. Reason : Aryl halides do not undergo nucleophilic substitution reaction. choose the correct answer from the options given below:
(1)Both (A) and (R) true but (R) is not the correct explanation of (A).
(2)(A) is false but (R) is true.
(3)Both (A) and (R) true and (R) is correct explanation of (A).