121.Which is the correct order of increasing energy of the listed orbitals in the atom of titanium? (At. no. Z=22)- (1)4s 3s 3p 3d
- (2)3s 3p 3d 4s
- (3)3s 3p 4s 3d
- (4)3s 4s 3p 3d
122.The wavelength of photon ' A ' is 400 nm. The frequency of photon ' B ' is 1016s−1. The wave number of photon ' C’ is 104cm−1. The correct order of energy of these photons is:- (1)C>B>A
- (2)B > A > C
- (3)A > B > C
- (4)A > C > B
123.Electronic configuration of calcium atom can be written as- (1)[Ne] 4p2
- (2)[Ar] 4s2
- (3)[Ne] 4s2
- (4)[Kr] 4p2
124.Which of the following electronic configuration would be associated with the highest magnetic moment?- (1)[Ar]3d7
- (2)[Ar]3d8
- (3)[Ar]3d3
- (4)[Ar]3d6
125.The approximate ratio of the speed of light in vacuum to that of an electron in the first Bohr orbit of hydrogen atom is- (1)100:1
- (2)137:1
- (3)157:1
- (4)191:1
126.Uncertainity in position of a particle of 25 g in space is 10–15 m. Hence, Uncertainity in velocity (in m.sec–1) is: (plank’s constant, h = 6.6 ´ 10–34 Js)- (1)2.1 ´ 10–18
- (2)2.1 ´ 10–34
- (3)0.5 ´ 10–34
- (4)5.0 ´ 10–24
127.The electron in the hydrogen atom undergoes transition from higher orbitals to orbitals of radius 211.6 pm. This transition is associated with- (1)Paschen series
- (2)Brackett series
- (3)Lyman series
- (4)Balmer series
128.The numbers of d-electrons retained in Fe2+ (atomic number Fe = 26) ion is- (1)3
- (2)4
- (3)5
- (4)6
129.With what velocity must an electron travel, so that its momentum is equal to that of a photon of wavelength 663nm?- (1)1098m/s
- (2)109.8m/s
- (3)10.98m/s
- (4)1.098m/s
130.If the de Broglie wavelength of the electron in nth Bohr orbit in a hydrogenic atom is equal to 1.5 πa0 (a0 is Bohr radius), then the value of n/z is:- (1)0.75
- (2)0.40
- (3)1.0
- (4)1. 50
131.The electronic configuration of Cr3+ is- (1)[Ar]3d44s2
- (2)[Ar]3d34s0
- (3)[Ar]3d24s1
- (4)[Ar]3d54s1
132.The electronic configuration of Cu2+ ion is- (1)[Ar]3d84s1
- (2)[Ar]3d94s0
- (3)[Ar]3d74s2
- (4)[Ar]3d84s0
133.The electrons identified by quantum numbers n and λ: (1) n = 4, λ = 1 (2) n = 4, λ = 0 (3) n = 3, λ = 2 (4) n = 3, λ = 1 can be placed in order of increasing energy as :- (1)(3) < (4) < (2) < (1)
- (2)(4) < (2) < (3) < (1)
- (3)(2) < (4) < (1) < (3)
- (4)(1) < (3) < (2) < (4)
134.Two particles A and B are in motion. If the wavelength associated with ' A ' is 33.33nm, the wavelength associated with ' B ' whose momentum is 1/3rd of ' A ' is- (1)1.0×10−8m
- (2)2.5×10−8m
- (3)1.25×10−7m
- (4)1.0×10−7m
135.Which of the graphs shown below does not represent the relationship between incident light and the electron ejected from metal surface?- (1)
- (2)
- (3)
- (4)
136.Energy of an electron is given by E = –2.178 × 10–18 J(n2Z2). Wavelength of light required to excite an electron in an hydrogen atom from level n = 1 to n = 2 will be: (h = 6.62 × 10–34 Js and c = 3.0 × 108 ms–1- (1)1.214 × 10–7 m
- (2)2.816 × 10–7 m
- (3)6.500 × 10–7 m
- (4)8.500 × 10–7 m
137.The wavelength of electron in the first orbit of hydrogen atom is 3,3×10−10m. The kinetic energy of electron (in J ) is (h=6.6×10−34Js,me=9.0×10−31kg)- (1)3.33×10−17
- (2)1.11×10−18
- (3)2.22×10−18
- (4)2.22×10−17
138.The electronic configuration of Einsteinium is : (Given atomic number of Einsteinium =99 )- (1)[Rn]5f106d∘7s2
- (2)[Rn]5f136d∘7s2
- (3)[Rn]5f116d∘7s2
- (4)[Rn]5f126d∘7s2
139.The correct order of decreasing energy for the electrons whose quantum numbers n and l are given below, is A. n=5 and l=2 B. n=5 and l=0 C. n=4 and l=3 D. n=4 and l=1- (1)A>C>B>D
- (2)A > B > C > D
- (3)C > A > D > B
- (4)A > B > D > C
140.The number of d‐electrons in Fe(2+Z=26) is not equal to the number of electrons in which one of the following?- (1)d‐electrons in Fe
- (2)p‐electrons in Ne
- (3)s‐electrons in Mg
- (4)p‐electrons in Cl
141.Ejection of the photoelectron from metal in the photoelectric effect experiment can by stopped by applying 0.5 V when the radiation of 250 nm is used. The work function of the metal is :- (1)4 eV
- (2)5.5 eV
- (3)4.5 eV
- (4)5 eV
142.Which of the activities can be compared to the concept of quantisation?- (1)A car is travelling on the road
- (2)An apple is falling form the tree
- (3)A person can stand on any step of a stair case
- (4)Throwing a playing disc
143.What is the mass in gram of 1 atom of an element if its atomic mass is 10u ?- (1)2.06056×10−22g
- (2)1.06056×10−24g
- (3)1.66056×10−23g
- (4)3.66056×10−25g
144.The work function of a metal M is 6.3eV. The wave length of the incident radiation required to just eject the electrons from its surface (in nm) is- (1)102
- (2)330
- (3)197
- (4)310
145.According to Bohr's atomic theory : (A) Kinetic energy of electron is ∝n2Z2 (B) The product of velocity (v) of electron and principal quantum number (n), 'vn' ∝Z2. (C) Frequency of revolution of electron in an orbit is ∝n3Z3. (D) Coulombic force of attraction on the electron is ∝n4Z3. Choose the most appropriate answer from the options given below:- (1)(C) only
- (2)(A) and (D) only
- (3)(A) only
- (4)(A), (C) and (D) only
146.If the shortest wavelength in Lyman series of hydrogen atom is A, then the longest wavelength in Paschen series of He+ is:- (1)536A
- (2)59A
- (3)95A
- (4)736A
147.Which orbital among the following has zero radial nodes and 2 angular nodes?- (1)4s
- (2)3d
- (3)2p
- (4)5s
148.Given The mass of electron is 9.11×10−31kg, Planck constant is 6. 626×10−34Js, the uncertainty involved in the measurement of velocity within a distance of 0.1 Å is- (1)5.79×105ms−1
- (2)5.79×106ms−1
- (3)5.79×107ms−1
- (4)5.79×108ms−1
149.The de Broglie wavelength of a particle is 1000nm. What is its momentum? (h=6.6×10−34Js)- (1)6.6×10−25 J s m-1
- (2)6.6×10−25Jsm
- (3)6.6×10−28Jsm−1
- (4)6.6×10−26Jsm
150.The sum of electrons present in all sub shells of an atom with ms value of +21 for n=4 and ms value of −21 for n=3 is- (1)25
- (2)16
- (3)09
- (4)32
|