271.An aromatic compound ‘A’ having molecular formula C7H6O2 on treating with aqueous ammonia and heating forms compounds ‘B’. The compound B on reaction with molecular bromine and potassium hydroxide provides compound ‘C’ having molecular formula C6H7N. The structure of ‘A’ is:- (1)
- (2)
- (3)
- (4)
272.The major product [B] in the following sequence of reactions is :- (1)CH2=C(CH(CH3)2)−CH2CH2CH3
- (2)CH3−C(CH(CH3)2)=CH−CH2CH3
- (3)
- (4)CH2−CH(CH(CH3)2)−CH=CH−CH3
273.In the above chemical reaction sequence " A " and " B " respectively are- (1)H2O,H+and KMnO4
- (2)O3,Zn/H2O and NaOH(alc)/I2
- (3)O3,Zn/H2O and KMnO4
- (4)H2O,H+and NaOH(alc)/I2
274.The major product formed in the following reaction is H3C−C≡C−CH3+Na→LiquidNH3- (1)H3C−CH2−C≡C−Na+
- (2)H3C−C≡C−CH2−Na−
- (3)
- (4)
275.The final product A, formed in the following reaction sequence is:- (1)Ph−CH2−CH2−CH3
- (2)Ph−CH(CH3)−CH3
- (3)Ph−CH(CH2OH)−CH3
- (4)Ph−CH2−CH2−CH2−OH
276.The major products P and Q in the following reactions, respectively, are
P Q- (1)Alkene (cis)
Alkene (cis) - (2)Alkane
Alkene (trans) - (3)Alkene (cis)
Alkene (trans) - (4)Alkene (trans)
Alkene (trans)
277.Number of possible alkynes with formula C5H8 is- (1)3
- (2)5
- (3)2
- (4)4
278.Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A react with Br2 to form product B. A and B are respectively:- (1)
- (2)
- (3)
- (4)
279.Choose the correct option for the following reactions.- (1)'A' and 'B' are both Markovnikov addition products.
- (2)'A' is Markovnikov product and 4ET is anti-Markovnikov product.
- (3)'A' and 'B' are both anti-Markovnikov products.
- (4)'B' is Markovnikov and 'A' is anti-Markovnikov product.
280.The major product (Y) in the following reactions is:- (1)CH3−C(CH3)=C(CH2−CH3)−CH3
- (2)CH3−CH(CH3)−C(CH2−CH3)=CH2
- (3)CH3−C(=CH2)−CH(CH2−CH3)−CH3
- (4)CH3−CH(CH3)−C(CH3)=CH−CH3
281.Consider the following reaction:
The product Y formed is:- (1)5-methylhex-2-yne
- (2)Isopropylbut-1-yne
- (3)2-methylhex-3-yne
- (4)2-methylhex-2-yne
282.In Friedel-Crafts alkylation of aniline, one gets :- (1)alkylated product with ortho and para substitution.
- (2)secondary amine after acidic treatment.
- (3)an amide product.
- (4)positively charged nitrogen at benzene ring.
283.An organic compound A upon reacting with NH3 gives B. On heating B gives C. C in presence of KOH reacts with Br2 to given CH3CH2NH2. A is :- (1)CH3COOH
- (2)CH3CH2CH2COOH
- (3)CH3−CH(CH3)−COOH
- (4)CH3CH2COOH
284.An alkene X(C6H12) on ozonlysis gave acetaldehyde and ethyl methyl ketone. What is the product formed when X reacts with HBr ?- (1)
- (2)
- (3)
- (4)
285.The product(s) of the following reaction sequence is(are)- (1)
- (2)
- (3)
- (4)
286.Identify X and Y in the following reaction sequence X→ZnY→O3Zn−H2O(CH3)2CO+CH2O- (1)X−(CH3)2BrCHCH3 , Y−CH3CH=CHCH3
- (2)X−(CH3)2CHCH2Br,Y−CH3CH=CHCH3
- (3)X−(CH3)2CBrCH2Br,Y−(CH3)2C=CH2
- (4)X−(CH3)2CHCHBr2,Y−(CH3)2C=CH2
287.The product(s) formed when toluene is reacted with Cl2 in presence of Fe in dark is/are- (1)
- (2)
- (3)
- (4)
288.Reaction of 2-methylbuta-1, 3-diene with O3 and Zn− H2O, gives- (1)CH3COCH3+2CO2↑
- (2)CH3COCHO+2HCHO
- (3)CH3COCHO+2HCO2H
- (4)CH3CO2H+3HCO2H
289.Identify A and B in the following reaction sequence.- (1)
- (2)
- (3)
- (4)
290.What are the suitable conditions for the following transformation?- (1)KMnO4−H2SO4/Δ
- (2)O3/O2,Zn+H2O
- (3)OsO4
- (4)Pb(OAc)4
291.Which of the following reactions is not correct?- (1)CH2Br−CH2Br→ZnCH2=CH2
- (2)
- (3)CH3−C≡C−H→H2OHg+2,H+CH3−CH2−CHO
- (4)Ph−CH2−Br→NadryetherPh−(CH2)2−Ph
292.The major product of the following reaction is: (1)HCl(2)AlCl3(Anhyd.)- (1)
- (2)
- (3)
- (4)
293.What is X is the following reaction sequence?- (1)
- (2)
- (3)
- (4)
294.2,3‐Dimethyl‐2‐butene can be prepared by heating which of the following compounds with a strong acid?- (1)(CH3)3CCH=cH2
- (2)(CH3)2c=cHCH2CH3
- (3)(CH3)2CHCH2CH=cH2
- (4)(CH3)2CH−CH(CH3)−CH=CH2
295.In a reaction of aniline a coloured products C was obtained. The structure of C would be :- (1)
- (2)
- (3)
- (4)
296.In the following reaction sequence, [C] is- (1)
- (2)
- (3)
- (4)
297.The major products 'A' and 'B' respectively, areCH3 1A'«-^:-HJC-C = CH2 -iga-VB' OH^ Lri^ CH~- (1)H3C−C(CH3)(OSO3H)−CH3 & CH3−C(CH3)=CH−C(CH3)(CH3)−CH3
- (2)CH3−C(CH3)=CH−C(CH3)(CH3)−CH3 & CH3−C(CH3)(OSO3H)−CH3
- (3)CH3−CH(CH3)−CH2CH2−CH(CH3)−CH3 & H3C−C(CH3)(OSO3H)−CH3
- (4)H3C−C(CH3)(OSO3H)−CH3 & CH3−CH(CH3)−CH2CH2−HC(CH3)−CH3
298.1-chloro-3-methylbutane on reaction with zinc and dilute hydrochloric acid gives______ as the major product.- (1)2-methylbutane
- (2)2-methylbutene
- (3)n-pentane
- (4)n-pentene
299.The major product of the following reaction is: CH3C≡CH(i)DCl(1equiv.)(ii)Dl- (1)CH3CD(I)CHD(Cl)
- (2)CH3CD(Cl)CHD(I)
- (3)CH3CD2CH(Cl)(I)
- (4)CH3C(I)(Cl)CHD2
300.Which one of the following alkenes when treated with HCl yields majorly an anti Markovnikov product ?- (1)CH3I−CH=CH2
- (2)Cl−CH=CH2
- (3)H2N−CH=CH2
- (4)F3C−CH=CH2
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