31.What are X and Y respectively in the following reactions X+D2O→C2D2+PY+D2O→CD4+Q- (1)AlCl3,CaCl2
- (2)Be2C,Al4C3
- (3)Al4C3,CaC2
- (4)CaC2,Al4C3
32.Among the following the correct statements are I. LiH,BeH2 and MgH2 are saline hydrides with significant covalent character II. Saline hydrides are volatile III. Electron - precise hydrides are Lewis bases IV. The formula for chromium hydride is CrH The correct option is- (1)I, III only
- (2)II, IV only
- (3)I, IV only
- (4)III, IV only
33.The metal salts formed during softening of hardwater using Clark's method are :- (1)Ca(OH)2 and Mg(OH)2
- (2)CaCO3 and Mg(OH)2
- (3)Ca(OH)2 and MgCO3
- (4)CaCO3andMgCO3
34.What is the approximate volume (in mL ) of 10volH2O2 solution that will react completely with 1L of 0.02M KMnO4 solution in acidic medium?- (1)56.05
- (2)113.5
- (3)90.8
- (4)75.75
35.Which one of the following methods is most suitable for preparing deionized water?- (1)Synthetic resin method
- (2)Clark's method
- (3)Calgon's method
- (4)Permutit method
36.When zeolite, which is hydrated sodium aluminium silicate is treated with hard water, the sodium ions are exchanged with- (1)H+ ions
- (2)Ca2+ ions
- (3)SO42– ions
- (4)OH–
37.The number of hydrogen bonds formed by a water molecule at normal conditions is- (1)1
- (2)2
- (3)3
- (4)4
38.The number of water molecules (s) not coordinated to copper ion directly in CuSO4⋅5H2O is:- (1)2
- (2)3
- (3)1
- (4)4
39.The hardness of a water sample (in terms of equivalents of (CaCO3) containing 10−3MCaSO4 is:( molar mass of (CaSO4=136gmol−1)- (1)10ppm
- (2)50 ppm
- (3)90ppm
- (4)100ppm
40.Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R. Assertion A : Hydrogen is the most abundant element in the Universe, but it is not the most abundant gas inthe troposphere. Reason R: Hydrogen is the lightest element. In the light of the above statements, choose the correct answer from the given below:- (1)A is false but R is true
- (2)Both A and R are true and is the correct explanation of A.
- (3)A is true but R is false.
- (4)Both A and R are true but is NOT the correct explanation of A.
41.A compound (MO2) of group I element (M) hydrolysed to form M+,OH−,X and Y. When X reacts with I2 in basic medium the products formed are I−, water and Y. Then X and Y are respectively- (1)H2O2,O2
- (2)H2O2,O3
- (3)H2,O2
- (4)O2,H2
42.The number of water molecules present in borax, kernite and bauxite respectively are- (1)10,4,2
- (2)5,1,2
- (3)4,2,3
- (4)10,4,10
43.The maximum number of hydrogen bonds that a molecule of water can have is- (1)3
- (2)4
- (3)1
- (4)2
44.Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Assertion A: Hydrogen is an environment friendly fuel Reason R: Atomic number of hydrogen is 1 and it is a very light element. In the light of the above statements, choose the correct answer from the options given below- (1)A is true but R is false
- (2)Both A and R are true but R is NOT the correct explanation of A
- (3)A is false but R is true
- (4)Both A and R are true and R is the correct explanation of A
45.The correct statements among the following are(A) BeH2 and MgH2 are polymeric in nature(B) LiH is unreactive to oxygen, at moderate temperatures(C) BeH2 and MgH2 possesses significant covalent character(D) the stability of alkali hydrides follows the order LiH<NaH<KH<RbH<CsH- (1)A,B,C,D
- (2)A, C only
- (3)A, C, D only
- (4)A, B, C only
46.The number of hydrogen molecules possible from its isotopes is- (1)3
- (2)6
- (3)1
- (4)4
47.Which of the following forms of hydrogen emits low energyβ− particles?- (1)Proton H+
- (2)Deuterium 12H
- (3)Protium11H
- (4)Tritium 13H
48.Hydrogen peroxide is stored away from light because it can get decomposed when exposed to light as- (1)H2O and O2
- (2)H2 and O2
- (3)H2O and H2
- (4)H2O and O3
49.Polyphosphates are used as water softening agents because they- (1)form soluble complexes with anionic species.
- (2)precipitate anionic species.
- (3)form soluble complexes with cationic species.
- (4)precipitate cationic species.
50.In which of the following substances will hydrogen bonds be strongest?- (1)HCl
- (2)H2O
- (3)Hl
- (4)H2S
51.Consider the following statements about the hydrides (I) Sodium hydride with water liberates oxygen gas (II) Methane, silane are examples of electron precise hydrides (III)Ammonia and water molecules are examples of electron deficient hydrides (IV)Hydrides of beryllium and magnesium are polymeric in structure The correct statements are- (1)I & II only
- (2)III & IV only
- (3)II & IV only
- (4)I & IV only
52.Given below are two statements : Statement −I: The process of producing syn-gas is called gasification of coal. Statement −II: The composition of syn-gas is CO + CO2 + H2(1 : 1 : 1) In the light of the above statements, choose the most appropriate answer from the options given below :- (1)Statement –I is false but Statement –II is true
- (2)Statement –I is true but Statement –II is false
- (3)Both Statement –I and Statement –II are false
- (4)Both Statement –I and Statement –II are true
53.Given below are two statements: Statement I : Nickel is being used as the catalyst for producing syn gas and edible fats. Statement II : Silicon forms both electron rich and electron deficient hydrides. In the light of the above statements, choose the most appropriate answer from the options given below;- (1)Both the statements I and II are correct
- (2)Statement I is incorrect but statement II is correct
- (3)Both the statements I and II are incorrect
- (4)Statement I is correct but statement II is incorrect
54.Which one of the following reactions indicates the reducing ability of hydrogen peroxide in basic medium ?- (1)HOC1 + H2O2 →H3O+ + Cl− + O2
- (2)PbS + 4H2O2 → PbSO4 + 4H2O
- (3)2MnO4−+3H2O2 →2MnO2 +3O2 +2H2O + 2OH−
- (4)Mn2+ + H2O2 → Mn4+ + 2OH−
55.Among the following, the correctly matched pair is- (1)electron deficient hydride - SiH4
- (2)saline hydride - CrH
- (3)electron precise hydride - HF
- (4)electron rich hydride −NH3
56.What is the volume (in mL ) of 20volH2O2 required to completely react with 500mL of 0.02M acidified KMnO4 solution?- (1)14.0
- (2)7.0
- (3)28.0
- (4)42.0
57.What will be the organic compound formed, when aluminium carbide react with deuterated water?- (1)CD3OD
- (2)DCOOD
- (3)CD4
- (4)D3C−O−CD3
58.Dihydrogen of high purity (>99.95%) is obtained through- (1)the electrolysis of acidified water using Pt electrodes.
- (2)the electrolysis of warm Ba(OH)2 solution using Ni electrodes.
- (3)the electrolysis of brine solution.
- (4)the reaction of Zn with dilute HCl.
59.Given below are two statementsAssertion (A): Protium and deuterium differ in their rates of reactions.Reason (R): They have different enthalpies of bond dissociation.The correct answer is- (1)Both (A) and (R) are correct and, (R) is the correct explanation of (A)
- (2)Both (A) and (R) are correct but (R) is not the correct explanation of (A)
- (3)(A) is correct but (R) is incorrect
- (4)(A) is incorrect but (R) is correct
60.The one that is NOT suitable for the removal of permanent hardness of water is :- (1)Calgon’s method
- (2)Ion-exchange method
- (3)Clark’s method
- (4)Treatment with sodium carbonate
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