1.Inert gases have positive electron gain enthalpy. Its correct order is- (1)Xe < Kr < Ne < He
- (2)He<Ne<Kr<Xe
- (3)He<Xe<Kr<Ne
- (4)He<Kr<Xe<Ne
2.The group having isoelectronic species is:- (1)O–, F–, Na, Mg+
- (2)O2–, F–, Na, Mg2+
- (3)O–, F–, Na+, Mg2+
- (4)O2–, F–, Na+, Mg2+
3.For one of the element various successive ionization enthalpies (in kJmol−1 ) are given below : I.E. 1st 2nd 3rd 4th 5th
577.5 1810 2750 11,580 14,820 The element is- (1)P
- (2)Mg
- (3)Si
- (4)Al
4.In which of the following the elements are in correct order of their chemical reactivity in terms of oxidizing property?- (1)F>O>Cl>N
- (2)O>F>Cl>N
- (3)Cl>F>O>N
- (4)F>Cl>N>O
5.For electron gain enthalpies of the elements denoted as ∆egH, the incorrect option is :- (1)∆egH (Cl) < ∆egH (F)
- (2)∆egH (Se) < ∆egH (S)
- (3)∆egH (I) < ∆egH (At)
- (4)∆egH (Te) < ∆egH (Po)
6.The correct statements among I to III regarding group 13 element oxides are, (I) Boron trioxide is acidic. (II) Oxides of aluminium and gallium are amphoteric. (III) Oxides of indium and thallium are basic.- (1)(I) and (II) only
- (2)(I), (II) and (III)
- (3)(I) and (III) only
- (4)(II) and (III) only
7.Assertion: The first ionization energy of Be is greater than that of B. Reason: 2p orbital is lower in energy than 2s.- (1)Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
- (2)Both Assertion and Reason are true but Reason is not correct explanation of Assertion.
- (3)Assertion is true but Reason is false.
- (4)Assertion is false but Reason is true.
8.The correct order of bond dissociation enthalpy of halogen is :- (1)F2>Cl2>Br2>I2
- (2)Cl2>F2>Br2>I2
- (3)Cl2>Br2>F2>I2
- (4)I2>Br2>Cl2>F2
9.Given below are two statements : Statement (I) : Both metal and non-metal exist in p and d-block elements. Statement (II) : Non-metals have higher ionisation enthalpy and higher electronegativity than the metals. In the light of the above statements, choose the most appropriate answer from the option given below:- (1)Both Statement I and Statement II are false
- (2)Statement I is false but Statement II is true
- (3)Statement I is true but Statement II is false
- (4)Both Statement I and Statement II are true
10.The second ionisation energies of Li,Be,B and C are in the order_____- (1)Li>C>B>Be
- (2)Li> B > C > Be
- (3)Be>C>B>Li
- (4)B>C>Be>Li
11.Identify the incorrect match
Name IUPAC Official Name A. Unnilunium (i) Mendelevium B. Unniltrium (ii) Lawrencium C. Unnilhexium (iii) Seaborgium D. Unununnium (iv) Darmstadtium- (1)(B), (ii)
- (2)(C), (iii)
- (3)(D), (iv)
- (4)(A), (i)
12.Consider the elements Ne,Na,Mg. The element with highest first ionization enthalpy and element with lowest second ionization enthalpy respectively are- (1)Na,Ne
- (2)Ne,Mg
- (3)Na,Na
- (4)Mg,Na
13.The lanthanide contraction is responsible for the fact that:- (1)Zr and Y have about the same radius
- (2)Zr and Nb have similar oxidation state
- (3)Zr and Hf have about the same radius
- (4)Zr and Zn have same oxidation state.
14.The correct order of the first ionization enthalpy is- (1)Al>Ga>Tl
- (2)Ga>Al>B
- (3)Tl>Ga>Al
- (4)B>Al>Ga
15.The electron affinity value are negative for A. Be→Be− B. N→N− C. O→O2− D. Na→Na− E.Al→Al−Choose the most appropriate answer from the options given below :- (1)D and E only
- (2)A, B and C only
- (3)A and D only
- (4)A, B, D and E only
16.The ionic radii (in Å) of N3−, O2− and F− are respectively :- (1)1.36, 1.40 and 1.71
- (2)1.36, 1.71 and 1.40
- (3)1.71, 1.40 and 1.36
- (4)1.71, 1.36 and 1.40
17.With which of the following electronic configuration an atom has the lowest ionisation enthalpy?- (1)1s22s22p3
- (2)1s22s22p53s1
- (3)1s22s22p6
- (4)1s22s22p5
18.The increasing order of the first ionization enthalpies of the elements B, P, S and F (lowest first) is:- (1)F < S < P < B
- (2)P < S < B < F
- (3)B < P < S < F
- (4)B < S < P < F
19.Which one among the following statements is/are not correct? I. Ba compounds, generally are more covalent than Be compounds. II. The electron gain enthalpy of He is positive. III. The oxidation state of O in OF2 and Na2O are same. IV. The radius of Na+ion is smaller than that of F−ion.- (1)I, III, IV
- (2)II
- (3)II, III, IV
- (4)I, III
20.The correct order of metallic character is- (1)K > Be > Ca
- (2)Be > Ca > K
- (3)Ca > K > Be
- (4)K > Ca > Be
21.The correct order of the atomic radii of C,Cs,Al, and Sis :- (1)C<S<A1<Cs
- (2)S<C<Cs<Al
- (3)S<C<Al<Cs
- (4)C<S<Cs<Al
22.The incorrect statement among the following is:- (1)the first ionization energy of Al is less than first ionization energy of Mg.
- (2)the second ionization energy of Mg is greater than second ionization energy of Na.
- (3)the first ionization energy of Na is less than first ionization energy of Mg
- (4)the third ionization energy of Mg is greater than third ionization energy of Al.
23.The first ionisation energies (in kJmol−1 ) of four consecutive elements of the second period are given in the options. The first ionisation energy of nitrogen is- (1)1086
- (2)1402
- (3)1681
- (4)1314
24.Match the LIST-I with LIST-II (Family) (Symbol of Element)| LIST-I | LIST-II |
|---|
| A. Pnictogen (group 15) | I. Ts | | B. Chalcogen | II. | Og C. Halogen III. Lv D. Noble gas IV. Mc Choose the correct answer from the options given below:- (1)A-IV, B-I, C-II, D-III
- (2)A-IV, B-III, C-I, D-II
- (3)A-III, B-I, C-IV, D-II
- (4)A-II, B-III, C-IV, D-I
25.In period 4 of the periodic table, the elements with highest and lowest atomic radii are respectively.- (1)Rb & Br
- (2)K & Se
- (3)K & Br
- (4)Na & Cl
26.Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is :- (1)Mg < Ca < Cl < P
- (2)Cl < P < Mg < Ca
- (3)P < Cl < Ca < Mg
- (4)Ca < Mg < P < Cl
27.Which of the following is not a periodic property?- (1)Atomic size
- (2)Electron affinity
- (3)Radioactivity
- (4)Ionisation potential
28.Identify the elements and using the ionisation energy values given below: Ionization Energy (kJ/mol) 1st 2nd X 495 4563 Y 731 1450- (1)X =Na; Y=Mg
- (2)X=Mg; Y=F
- (3)X=Mg; Y=Na
- (4)X=F; Y=Mg
29.Which of the following statements are not correct? (A) The electron gain enthalpy of F is more negative than that of Cl. (B) lonization enthalpy decreases in a group of periodic table. (C) The electronegativity of an atom depends upon the atoms bonded to it. (D) A12O3 and NO are examples of amphoteric oxides. Choose the most appropriate answer from the options given below:- (1)A, B, C and D
- (2)A, B and D only
- (3)B and D only
- (4)A, C and D only
30.Match the following: List-I (Atomic number)A. 56B. 50C. 27D. 58List – II (Group number & Period number)I. 9,4II. 3,6III. 14,5IV. 2,6- (1)A-III; B-IV; C-I; D-II
- (2)A-II; B-III; C-IV; D-I
- (3)A-IV; B-I; C-II; D-III
- (4)A-IV; B-III; C-I; D-II
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