JEE · NEET Previous Year Question

Match the LIST-I with LIST-II (al ph e)
(Reagent)
(Functional Group detected)
LIST-ILIST-II
A. Sodium bicarbonate solutionI. Double bond /unsaturation
B. Neutral ferric chlorideII.
carboxylic acid
C.
ceric ammonium nitrate
III.
phenolic - OH
D.
alkaline
IV.
alcoholic - OH
Choose the correct answer from the options given below:

Topic: JEE PYQ

Answer: D. Full step-by-step solution below.

  1. AA-II, B-III, C-I, D-IV
  2. BA-II, B-IV, C-III, D-I
  3. CA-III, B-II, C-IV, D-I
  4. DA-II, B-III, C-IV, D-I

Correct answer: D

Solution

(d)
(A) Carboxylic acid gives efferve scence with sodium bicarbonate solution
(B) Phenolic-OH gives voilet coloured complex with Neutral .
(C) Alcoholic-OH gives Red colour with cerric ammonium Nitrate.
(D) When alkaline reacts with an unsaturated compound (Alkene or alkyne) the purple colour of solution disappears, indicating positive test for unsaturation.

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