JEE · NEET Previous Year Question

Given below are two statements:
Statement (I): The boiling points of alcohols and phenols increase with increase in the number of C-atoms.
Statement (II): The boiling points of alcohols and phenols are higher in comparison to other class of compounds such as ethers, haloalkanes.
choose the correct answer from the options given below:

Topic: JEE PYQ

Answer: B. Full step-by-step solution below.

  1. ABoth Statement I and Statement II are false
  2. BBoth Statement I and Statement II are true
  3. CStatement I is false but Statement II is true
  4. DStatement I is true but Statement II is false

Correct answer: B

Solution

(b) Statement I is correct as boiling point of alcohol phenols increase with increase in the
number of -atoms due to increase in van der Waals forces. Statement II is correct, since alcohols phenols have intermolecular H -bonding therefore their boiling points are higher in comparison to other class of compounds such as ethers, haloalkanes.

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