JEE · NEET Previous Year Question

The correct statement regarding a carbonyl compound with a hydrogen atom on its alpha-carbon, is :

Topic: NEET PYQ

Answer: A. Full step-by-step solution below.

  1. Aa carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this processes is known as keto-enol tautomerism .
  2. Ba carbonyl compound with a hydrogen atom on its alpha-carbon never equilibrates with its corresponding enol.
  3. Ca carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as aldehyde-ketone equilibration.
  4. Da carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known a carbonylation.

Correct answer: A

Solution

(a) It is known that basic need for the existance of Keto-enol tautomers is the presence of at least one hydrogen atom at adjacent sp3 carbon of carbonyl carbon.

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