151.Assertion : Addition of bromine to trans-2-butene yields meso-2. 3-dibromobutane. Reason : Addition of bromine to an alkene is an electrophilic addition.- (1)Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
- (2)Both Assertion and Reason are true but Reason is not correct explanation of Assertion.
- (3)Assertion is true but Reason is false.
- (4)Assertion is false but Reason is true.
152.Presence of halogen in organic compounds can be detected using- (1)Leibigs' test
- (2)Kjeldahl's test
- (3)Duma's test
- (4)Beilstein's test.
153.Which one of the following shows functional isomerism?- (1)C2H4
- (2)C2H5OH
- (3)C3H6
- (4)CH2Cl2
154.Identify correct statements from the following :(A) Propanal and propanone are functional isomers.(B) Ethoxyethane and methoxypropane are metamers.(C) But-2-ene shows optical isomerism.(D) But-1-ene and but-2-ene are functional isomers.(E) Pentane and 2, 2-dimethyl propane are chain isomers. Choose the correct answer from the options given below:- (1)(A) (B) and (C) only
- (2)(B) (C) and (D) only
- (3)(C) (D) and (E) only
- (4)(A) (B) and (E) only
155.Given below are two statements: Statement I: In Lassaigne's test, the covalent organic molecules are transformed into ionic compounds. Statement II: The sodium fusion extract of an organic compound having N and S gives prussian blue colour with FeSO4 and Na4(Fe(CN)6) choose the correct answer from the options given below.- (1)Statement I is true but Statement II is false
- (2)Both Statement I and Statement II are false
- (3)Both Statement I and Statement II are true
- (4)Statement I is false but Statement II is true
156.In the Kjeldahl’s method for estimation of nitrogen present in a soil sample, ammonia evolved from 0.75 g of sample neutralized 10 mL ofl MH2SO4. The percentage ofnitrogen in the soil is- (1)37.33
- (2)45.33
- (3)35.33
- (4)43.33
157.Which of the following will have a meso-isomer also ?- (1)2-Chlorobutane
- (2)2,3-Dichlorobutane
- (3)2,3-Dichloropentane
- (4)2-Hydroxypropanoic acid
158.The predominant form of histamine present in human blood is (pKa, Histidine = 6.0)- (1)
- (2)
- (3)
- (4)
159.Consider the following reaction
Identify the structure of the major product ‘X’.- (1)H3C−CH(D)−CH(CH3)−C˙H2
- (2)H3C−CH(D)−C˙(CH3)−CH3
- (3)H3C−C˙(D)−CH(CH3)−CH3
- (4)H3C−C˙H−CH(CH3)−CH3
160.The number of σ bonds, π bonds and lone pair of electrons in pyridine, respectively are- (1)12,2,1
- (2)11,2,0
- (3)12,3,0
- (4)11,3,1
161.Stability order of following alkoxide ions is- (1)C>B>A
- (2)A>C>B
- (3)B>A>C
- (4)C>A>B
162.Match items of column I and II Column I (Mixture of compounds)(A). H2 O/ CH2C12(B).(C). Kerosene/ Naphthalene(D). C6H12O6 /NaClColumn II (Separation Technique)(I). Crystallization(II). Differential solvent extraction(III). Column chromatography(IV). Fractional Distillation Correct match is :- (1)A-(III), B-(IV), C-(II), D-(I)
- (2)A-(I), B-(III), C-(II), D-(IV)
- (3)A-(II), B-(III), C-(IV), D-(I)
- (4)A-(II), B-(IV), C-(I), D-(III)
163.Which amongst the following is the strongest acid ?- (1)CHBr3
- (2)CHCl3
- (3)CHI3
- (4)CH(CN)3
164.The IUPAC name of the following molecule is- (1)2-Methyl-5 nitro-1-chlorobenzene
- (2)3-Chloro-4 methyl-1-nitrobenzene
- (3)2-Chloro-1 methyl-4-nitorbenzene
- (4)2-Chloro-4 nitro-1-methylbenzene
165.The IUPAC name of the compound having the formula CH≡C−CH=cH2 is- (1)l‐butyne‐3‐ene
- (2)but‐l‐yne‐3‐ene
- (3)l‐butene‐3‐yne
- (4)3‐butene‐l‐yne.
166.Arrange the following conformational isomers of n-butane in order of their increasing potential energy :- (1)II < III < IV < I
- (2)I < IV < III < II
- (3)II < IV < III < I
- (4)I < III < IV < II
167.Rate of the reaction is fastest when Z is :- (1)Cl
- (2)OCOCH3
- (3)OC2H5
- (4)NH2
168.The increasing order of pKb for the following compounds will be : (A) NH2–CH=NH, (B) (C) CH3–NH–CH3- (1)(A) < (B) < (C)
- (2)(B) < (C) < (A)
- (3)(B) < (A) < (C)
- (4)(C) < (A) < (B)
169.Which of the following species does not exert a resonance effect?- (1)C6H5OH
- (2)C6H5NH2
- (3)C6H5Cl
- (4)C6H5NH3
170.Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : Cis form of alkene is found to be more polar than the trans form. Reason (R): Dipole moment of trans isomer of 2-butene is zero.In the light of the above statements, choose the correct answer from the options given below :- (1)(A) is false but (R) is true
- (2)Both (A) and (R) are true and (R) is the correct explanation of (A)
- (3)(A) is true but (R) is false
- (4)Both (A) and (R) are true but (R) is NOT the correct explanation of (A)
171.The correct order of increasing acid strength of the compounds. (A) CH3CO2H (B) MeOCH2CO2H (C) CF3CO2H (D) is- (1)B < D < A < C
- (2)D < A < C < B
- (3)D < A < B < C
- (4)A < D < C < B
172.Consider the following compounds : Hyperconjugation occurs in- (1)III only
- (2)I and III
- (3)I only
- (4)II only
173.Match List I with List II. List I Isomeric pairsA. Propanamine and N-MethylethanamineB. Hexan-2-one and Hexan-3-oneC. Ethanamide and HydroxyethanimineD. o-nitrophenol and p-nitrophenolList II Type of isomersI. MetamersII. Positional isomersIII. Functional isomersIV. Tautomers Choose the correct answer from the options given below :-- (1)A-III,B-IV,C-I,D-II
- (2)A-IV, B-III, C-I, D-II
- (3)A-II, B-III, C-I, D-IV
- (4)A-III, B-I, C-IV, D-II
174.IUPAC name of the following is CH2=CH−CH2−CH2−C≡CH- (1)1,5‐hexenyne
- (2)l‐hexene‐5‐yne
- (3)1‐hexyne −5‐ene
- (4)1,5‐hexynene.
175.The stability of carbanions in the following.
is in the order of- (1)(iv) >(ii)>(iii)>(i)
- (2)(i)>(iii)>(ii)>(iv)
- (3)(i)>(ii)>(iii)>(iv)
- (4)(ii) >(iii)>(iv)>(i)
176.The Kjeldahl's method for the estimation of nitrogen can be used to estimate the amount of nitrogen in which one of the following compounds?- (1)
- (2)
- (3)
- (4)
177.Thin layer chromatography of a mixture shows the following observation:
The correct order of elution in the silica gel column chromatography is- (1)B,A, C
- (2)B, C, A
- (3)A, C,B
- (4)C,A, B
178.Correct order of stability of carbanion is -- (1)d>a>c>b
- (2)a>b>c>d
- (3)d>c>b>a
- (4)c>b>d> a
179.Which of the following compound will exhibit geometrical isomerism ?- (1)1-Phenyl-2-butene
- (2)3-Phenyl-1-butene
- (3)2-Phenyl-1-butene
- (4)1,1-Diphenyl-1-propane
180.Which of the following compounds shall not produce propene by reaction with HBr followed by elimination or direct only elimination reaction ?- (1)H3C−CH2−CH2Br
- (2)
- (3)H3C−CH2−CH2OH
- (4)H2C=C=O
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