181.The correct IUPAC nomenclature for the following compound is:- (1)2-Methyl-5-oxohexanoic acid
- (2)2-Formyl-5-methylhexan-6-oic acid
- (3)5-Methyl-2-oxohexan-6-oic acid
- (4)5-Formyl-2-methylhexanoic acid
182.How many different stereoisomers are possible for the given molecule?- (1)2
- (2)1
- (3)4
- (4)3
183.Structure of the compound whose IUPAC name is 3‐Ethyl‐2‐hydroxy‐4‐methylhex‐3‐en‐ 5‐ynoic acid is- (1)
- (2)
- (3)
- (4)
184.Choose the correct name for compound given below:- (1)(4E)-5-Bromo-hex-4-en-2-yne
- (2)(2E)-2-Bromo-hex-4-yn-2-ene
- (3)(2E)-2-Bromo-hex-2-en-4-yne
- (4)(4E)-5-Bromo-hex-2-en-4-yne
185.Consider the acidity of the carboxylic acids: (i) PhCOOH (ii) o-NO2C6H4COOH (iii) p-NO2C6H4COOH (iv) m-NO2C6H4COOH- (1)i > ii > iii > iv
- (2)ii > iii > iv > i
- (3)iii > ii > iv > i
- (4)ii > iv > iii > i
186.Consider the following three resonance structures
The correct order of their stabilities is- (1)II > I > III
- (2)I > II > III
- (3)III > I > II
- (4)III > II > I
187.The species that can have a trans-isomer is: (en =ethane – 1, 2 – diamine, Ox = oxalate)- (1)(Zn(en)Cl2)
- (2)(Pt(en)Cl2)
- (3)(Cr(en)2(Ox))2
- (4)(Pt(en)2Cl2)2+
188.Nitrogen detection in an organic compound is carried out by Lassaigne’s test. The blue colour formed corresponds to which of the following formulae?- (1)Fe3[Fe(CN)6]2
- (2)Fe4[Fe(CN)6]3
- (3)Fe4[Fe(CN)6]2
- (4)Fe3[Fe(CN)6]3
189.The IUPAC name of the compound CH3CH=CHC≡CH is- (1)pent‐4‐yn‐2‐ene
- (2)pent‐3‐en‐l‐yne
- (3)pent‐2‐en‐4‐yne
- (4)pent‐l‐yn‐3‐ene
190.Compound from the following that will not produce precipitate on reaction with AgNO3 is- (1)
- (2)
- (3)
- (4)
191.The correct statement regarding the comparison of staggered and eclipsed conformations of ethane, is:- (1)The staggered conformation of ethane is more stable than eclipsed conformation, because staggered conformation has no torsional strain.
- (2)The staggered conformation of ethane is less stable than eclipsed conformation, because staggered conformation has torsional strain.
- (3)The eclipsed conformation of ethane is more stable than staggered conformation, because eclipsed conformation has no torsional strain.
- (4)The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has torsional strain.
192.Which one of the carbocations from the following is most stable?- (1)
- (2)
- (3)
- (4)
193.In Dumas method for the estimation of N2, the sample is heated with copper oxide and the gas evolved is passed over :- (1)Ni
- (2)Copper gauze
- (3)Pd
- (4)Copper oxide
194.A pair of compounds which shows geometelat isomerism is- (1)ethanol and acetone
- (2)n-butane and isobutene
- (3)dimethyl ether and ethanol
- (4)maleic acid and fumaric acid.
195.Amongst the following the most basic compound is- (1)p-Nitroaniline
- (2)Acetanilide
- (3)Aniline
- (4)Benzylamine
196.The most suitable method of separation of 1 : 1 mixture of ortho and para‐nitrophenols is- (1)chromatography
- (2)crystallisation
- (3)steam distillation
- (4)sublimation.
197.CH3Br + Nu– → CH3 – Nu + Br– The decreasing order of the rate of the above reaction with nucleophiles (Nu¯) A to D is :- (1)D > C > B > A
- (2)A > B > C > D
- (3)B > D > C > A
- (4)D > C > A > B
198.Relative stability of the contributing structures is :- (1)(I) > (II) > (III)
- (2)(I) > (III) > (II)
- (3)(II) > (I) > (III)
- (4)(III) > (II) > (I)
199.Among the following compounds the one that is most reactive towards electrophilic nitration is- (1)benzoic acid
- (2)nitrobenzene
- (3)toluene
- (4)benzene
200.Consider the reaction : CH3CH2CH2Br + NaCN CH3CH2CH2CN + NaBr This reaction will be the fastest in :- (1)water
- (2)ethanol
- (3)methanol
- (4)N,N’-dimethylformamide (DMF)
201.Which of the following is metamer of the given compound (X) ?- (1)C6H11-NH-CO-C6H5 (N-cyclohexylbenzamide)
- (2)C6H5-NH-CO-C6H5 (N-phenylbenzamide)
- (3)C6H11-NH-CO-C6H11 (N-cyclohexylcyclohexanecarboxamide)
- (4)4-(cyclohexylamino)benzaldehyde
202.In Carius method, halogen containing organic compound is heated with fuming nitric acid in the presence of :- (1)HNO3
- (2)AgNO3
- (3)CuSO4
- (4)BaSO4
203.Reaction of one molecule of HBr with one molecule of 1, 3-butadiene at 40°C gives predominantly- (1)3-bromobutene under kinetically controlled conditions
- (2)1-bromo-2-butene under thermodynamically controlled conditions
- (3)3-bromobutene under thermodynamically controlled conditions.
- (4)1-bromo-2-butene under kinetically controlled conditions.
204.Which one of the nitrogen atoms in is the most nucleophilic?- (1)III
- (2)I
- (3)II
- (4)All three nitrogen atoms are equally strong nucleophilic centers.
205.Match List I with List II List - I (Pair of compounds)(A) n-propanol and Isopropanol(B) Methoxypropane and ethoxyethane(C) Propanone and propanal(D) Neopentane and IsopentaneList - II (Isomerism)(I) Metamerism(II) Chain Isomerism(III) Position Isomerism(IV) Functional Isomerism Choose the correct answer from the options given below :- (1)(A)-(II), (B)-(I), (C)-(IV), (D)-(III)
- (2)(A)-(III), (B)-(I), (C)-(II), (D)-(IV)
- (3)(A)-(I), (B)-(III), (C)-(IV), (D)-(II)
- (4)(A)-(III), (B)-(I), (C)-(IV), (D)-(II)
206.Maximum dehydration takes place that of :- (1)
- (2)
- (3)
- (4)
207.The major product formed in the following reaction is :- (1)CH3−CH(CH3)−CH2OCH3
- (2)CH3−CH(OCH3)−CH2CH3
- (3)CH3−C(CH3)=CH2
- (4)CH3−C(CH3)(OCH3)−CH3
208.The IUPAC name of the following compound is :- (1)4-Bromo-3-cyanophenol
- (2)2-Bromo-5-hydroxybenzonitrile
- (3)2-Cyano-4-hydroxybromobenzene
- (4)6-Bromo-3-hydroxybenzonitrile
209.In the following skew conformation of ethane, H’−C−C−H’’ dihedral angle is:- (1)58°
- (2)149°
- (3)151°
- (4)120°
210.Considering the state of hybridization of carbon atoms, find out the molecule among the following which is linear?- (1)CH3–CH=CH–CH3
- (2)CH3–C≡C–CH3
- (3)CH2=CH–CH2–C≡CH
- (4)CH3–CH2–CH2–CH3
|