JEE · NEET Previous Year Question

An aqueous solution of HCl with pH 1.0 is diluted by adding equal volume of water (ignoring dissociation of water). The pH of HCl solution would (Given )

Topic: JEE PYQ

Answer: A. Full step-by-step solution below.

  1. Aincrease to 1.3
  2. Breduce to 0.5
  3. Cincrease to 2
  4. Dremain same

Correct answer: A

Solution

(a)
An aqueous solution of HCl initially has a pH of 1.0, meaning the hydrogen ion concentration is .
When we dilute the solution by adding an equal volume of water, the concentration of hydrogen ions will be halved:

To find the new pH , we use the pH formula:

Substituting the new hydrogen ion concentration gives:

Using the logarithm property :

Given , we need , which can be calculated as:
log 2 = 1 – 0.30 = 0.70
Thus:

Therefore, the pH of the solution increases to 1.3.

More Ionic Equilibrium PYQs