91.The ore that is concentrated by froth floatation process is- (1)cinnabar
- (2)bauxite
- (3)malachite
- (4)zincite.
92.In chromite ore, the oxidation number of iron, and chromium are respectively- (1)+3,+2
- (2)+3,+6
- (3)+2,+6
- (4)+2,+3
93.The alloy used in the construction of aircrafts is :- (1)Mg−Al
- (2)Mg−Zn
- (3)Mg−Sn
- (4)Mg−Mn
94.Statement I : Leaching of gold with cyanide ion in absence of air /O2 leads to cyano complex of Au(III). Statement II : Zinc is oxidized during the displacement reaction carried out for gold extraction.In the light of the above statements, choose the correct answer from the options given below.- (1)Both Statement I and Statement II are correct
- (2)Both Statement I and Statement II are incorrect
- (3)Statement I is correct but Statement II is incorrect
- (4)Statement I is incorrect but Statement II is correct
95.Electrolytic refining is used to purify which of the following metals?- (1)Cu and Zn
- (2)Ge and Si
- (3)Zr and Ti
- (4)Zn and Hg
96.During the extraction of gold the following reactions take place. Au+CN−+H2O→O2[X] [X]+Zn→[Y]+Au X and Y are respectively- (1)Au(CN)2-and (Zn(CN)6)4−
- (2)(Au(CN)4)2− and (Zn(CN)4)2−
- (3)(Au(CN)4)3− and (Zn(CN)4)2−
- (4)Au(CN)2-and (Zn(CN)4)2−
97.The function of Fe(OH)3 in the contact process is- (1)to detect colloidal impurity
- (2)to remove moisture
- (3)to remove dust particles
- (4)to remove arsenic impurity.
98.An Ellingham diagram provides information about- (1)the temperature dependence of the standard Gibbs energies of formation of some metal oxides
- (2)the pressure dependence of the standard electrode potentials of reduction reactions involved in the
extraction of metals - (3)the conditions of pH and potential under which a species is thermodynamically stable
- (4)the kinetics of the reduction process
99.Given below are two statements statements Statement I :- In froth floatation method a rotating paddle agitates the mixture to drive air out of it. Statement II :- Iron pyrites are generally avoided for extraction of iron due to environmental reasons. In the light of the above statements, choose the correct answer from the options given below :-- (1)Both Statement I and Statement II are true
- (2)Statement I is false but Statement II is true
- (3)Statement I is true but Statement II is false
- (4)Both Statement I and Statement II are false
100.Match the following items in column I with the corresponding items in column II.
Column-I
Column-II (i) Na2CO3⋅10H2O (A) Portland cementingredient (ii) Mg(HCO3)2 (B) Castner-Kellner process (iii) NaOH (C) Solvay process (iv) Ca3Al2O6 (D) Temporary hardness- (1)(i)→(B);(ii)→(C);(iii)→(A);(iv)→(D)
- (2)(i)→(C);(ii)→(B);(iii)→(D);(iv)→(A)
- (3)(i)→(D);(ii)→(A);(iii)→(B);(iv)→(C)
- (4)(i)→(C);(ii)→(D);(iii)→(B);(iv)→(A)
101.Match List –I with List – II List I (Metal)(1) Aluminium(2) Iron(3) Copper(4) ZincList II (Ores)(i) Siderite(ii) Calamine(iii) Kaolinite(iv) Malachite Choose the correct answer from the options given below:- (1)(1)-(iv), (2)-(iii), (3)-(ii), (4)-(i)
- (2)(1)-(i), (2)-(ii), (3)-(iii), (4)-(iv)
- (3)(1)-(iii), (2)-(i), (3)-(iv), (4)-(ii)
- (4)(1)-(ii), (2)-(iv), (3)-(i), (4)-(iii)
102.The statement that is INCORRECT about Ellingham diagram is- (1)provides idea about the reaction rate.
- (2)provides idea about free energy change.
- (3)provides idea about changes in the phases during the reaction.
- (4)provides idea about reduction of metal oxide.
103.In the Hall-Heroult process, aluminium is formed at the cathode. The cathode is made out of:- (1)Pure aluminium
- (2)Carbon
- (3)Copper
- (4)Platinum
104.The metal which is extracted by oxidation and subsequent reduction from its ore is :- (1)Al
- (2)Ag
- (3)Cu
- (4)Fe
105.“Metals are usually not found as nitrates in their ores.” Out of the following two (I and II) reasons which is/are true for the above observation? I. Metal nitrates are highly unstable. II. Metal nitrates are highly soluble in water.- (1)I is false but II is true.
- (2)I is true but II is false.
- (3)I and II are true.
- (4)I and II are false (2015, Cancelled)
106.Given are two statements one is labelled as Assertion A and other is labelled as Reason R. Assertion A :Magnesium can reduce A12O3 at a temperature below 1350°C, while above 1350°C aluminium can reduce MgO. Reason R : The melting and boiling points of magnesium are lower than those of aluminium. In light of the above statements, choose most appropriate answer from the options given below:- (1)Both A and R are correct, and R is correct explanation of A.
- (2)Both A and R are correct, but R is NOT the correct explanation of A.
- (3)A is correct R is not correct.
- (4)A is not correct. R is correct.
107.Sulphide ores of metals are usually concentrated by Froth floatation process. Which one of the following sulphide ores offers an exception and is concentrated by chemical leaching ?- (1)Sphalerite
- (2)Argentite
- (3)Galena
- (4)Copper pyrite
108.Al2O3was leached with alkali to get X. The solution of X on passing of gas Y, forms Z. X, Y and Z respectively are:- (1)X=Na(Al(OH)4),Y=CO2,Z=Al2O3∙xH2O
- (2)X=Na(Al(OH)4),Y=SO2,Z=Al2O3
- (3)X=Al(OH)3,Y=SO2,Z=Al2O3∙xH2O
- (4)X=Al(OH)3,Y=CO2,Z=Al2O3
109.The process which invovles the treatment of the ore with a suitable reagent so as to make it soluble but not impurities is called- (1)Froth floatation
- (2)Roasting
- (3)Hydrometallurgy
- (4)Leaching
110.The idea of froth floatation method came from a person X and this method is related to the process Y of ores, X and Y respectively, are:- (1)fisher woman and concentration
- (2)washer woman and concentration
- (3)fisher man and reduction
- (4)washer man and reduction
111.Sulfide ores are common for the metals :- (1)Ag, Cu and Pb
- (2)Ag, Cu and Sn
- (3)Ag, Mg and Pb
- (4)Al, Cu and Pb
112.The metal extracted by leaching with a cyanide is :- (1)Mg
- (2)Ag
- (3)Cu
- (4)Na
113.Extraction of gold and silver involves leaching with CN– ion. Silver is later recovered by :- (1)liquation
- (2)distillation
- (3)zone refining
- (4)displacement with Zn
114.The correct statement regarding the given Ellinghamdiagram is:- (1)At 1400∘C,Al can be used for the extraction of Znfrom ZnO
- (2)At 500∘C, coke can be used for the extraction of Znfrom ZnO
- (3)Coke cannot be used for the extraction of Cufrom Cu2O
- (4)At 800∘C, Cu can be used for the extraction of Znfrom ZnO
115.The plot shows the variation of –ln Kp versus temperature for the two reactions. M(s) + 21O2(g) → MO(s) and C(s) + 21O2(g) → CO(s) Identify the correct statement:- (1)At T > 1200 K, carbon will reduce MO(s) to M(s).
- (2)At T < 1200 K, oxidation of carbon is unfavourable.
- (3)Oxidation of carbon is favourable at all temperatures.
- (4)At T < 1200 K, the reaction MO(s) + C(s) → M(s) + CO(g) is spontaneous
116.The reducing agent in the given equations:- (1)Zn
- (2)O2
- (3)H2O
- (4)CN−
117.Match List I with List II : (Both having metallurgical terms) Choose the correct answer from the options given below :- (1)(a)-(iii), (b)-(ii), (c)-(i), (d)-(iv)
- (2)(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
- (3)(a)-(iv), (b)-(i), (c)-(iii), (d)-(ii)
- (4)(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
118.Carbon cannot reduce Fe2O3 to Fe at a temperature below 983K because- (1)free energy change for the formation of CO is more negative than that of Fe2O3
- (2)CO is themodynamically more stable than Fe2O3
- (3)carbon has higher affinity towards oxygen than iron
- (4)iron has higher affinity towards oxygen than carbon.
119.ΔG∘ vs T plot in the Ellingham's diagram slopes downwards for the reactions- (1)Mg+O2→MgO
- (2)2Ag+O2→Ag2O
- (3)C+O2→CO
- (4)noneoftheabove
120.Aluminium is extracted from alumina (Al2O3) by electrolysis of a molten mixture of- (1)Al2O3+HF+NaAlF4
- (2)Al2O3+CaF2+NaAlF4
- (3)Al2O3+Na3AlF6+CaF2
- (4)Al2O3+KF+Na3AlF6 (2012)
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