JEE · NEET Previous Year Question
The lanthanide contraction is responsible for the fact that:
Topic: JEE PYQ
Answer: C. Full step-by-step solution below.
- AZr and Y have about the same radius
- BZr and Nb have similar oxidation state
- CZr and Hf have about the same radius
- DZr and Zn have same oxidation state.
Correct answer: C
Solution
(c) The atomic radii of the second and third transition series are almost the same. This phenomenon is associated with the intervention of the 4f orbitals which must be filled before the 5d series of elements begin. The filling of 4f before 5d orbital results in a regular decrease in atomic radii called Lanthanide contraction which essentially compensates for the expected increase in atomic size with increasing atomic number. The net result of the lanthanide contraction is that the second and the third d series exhibit similar radii (e.g., Zr 160 pm, Hf 159 pm).More Periodic Table & Periodicity PYQs
- Inert gases have positive electron gain enthalpy. Its correct order is
- The group having isoelectronic species is:
- For one of the element various successive ionization enthalpies (in ) are given below : I.E.…
- In which of the following the elements are in correct order of their chemical reactivity in terms of oxidizing property?
- For electron gain enthalpies of the elements denoted as H, the incorrect option is :