JEE · NEET Previous Year Question

Compounds that should not be used as primary standards in titrimetric analysis are(redox)
(A) (B) Oxalic acid(C) NaOH(D) (E) Sodium tetraborate
Choose the most appropriate answer from the options given below:

Topic: JEE PYQ

Answer: D. Full step-by-step solution below.

  1. AC, D and E Only
  2. BB and D Only
  3. CD and E Only
  4. DA, C and D Only

Correct answer: D

Solution

(d)
The primary standard is a highly pure stable compound with a known exact composition that can be accurately weighed and dissolved to creat a solution of known concentration.
NaOH is hygroscopic and can't be used.
is unstable and can be easily oxidised.
is hygroscopic and can't be used.

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