JEE · NEET Previous Year Question

The brown ring test for nitrates depends on

Topic: JEE PYQ

Answer: A. Full step-by-step solution below.

  1. Athe reduction of nitrate to nitric oxide
  2. Boxidation of nitric oxide to nitrogen dioxide
  3. Creduction of ferrous sulphate to iron
  4. Doxidising action of sulphuric acid.

Correct answer: A

Solution

(a) : The brown ring is appeared due to the formation of a brown complex between nitric oxide (formed as a result of reduction of the nitrate ion by the ions) and ions.



Pentaaquanitrosonium iron (I)
(Brown complex)

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