JEE · NEET Previous Year Question

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R:
Assertion A : Acetal/Ketal is stable in basic medium.
Reason R : The high leaving tendency of alkoxide ion gives the stability to acetal/ketal in basic medium.
choose the correct answer from the options given below:

Topic: JEE PYQ

Answer: A. Full step-by-step solution below.

  1. AA is true but R is false
  2. BA is false but R is true
  3. CBoth A and R are true and R is the correct explanation of A
  4. DBoth A and R are true but R is NOT the correct explanation of A

Correct answer: A

Solution

(a) For Assertion: Acetal and ketals are basically ethers hence they must be stable in basic medium but should break down in acidic medium. Hence assertion is correct. For reason: Alkoxide ion () is not considered a good leaving group hence reason must be false.

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