JEE · NEET Previous Year Question

Two statements are given below :
Statement I: The melting point of monocarboxylic acid with even number of carbon atoms is higher than that of with odd number of carbon atoms acid immediately below and above it in the series.
Statement II: The solubility of monocarboxylic acids in water decreases with increase in molar mass.
Choose the most appropriate option:

Topic: JEE PYQ

Answer: A. Full step-by-step solution below.

  1. ABoth Statement I and Statement II are correct.
  2. BBoth Statement I and Statement II are incorrect.
  3. CStatement I is correct but Statement II is incorrect.
  4. DStatement I is incorrect but Statement II is correct.

Correct answer: A

Solution

(a)
I . Better packing efficiency of monocarboxylic acids with even number of carbon atoms results in higher M.P
II. As molar mass increases hydrophobic part size increase hence solubility decreases.

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