JEE · NEET Previous Year Question

In which of the following molecules, the central atom does not have sp3 hybridization?

Topic: NEET PYQ

Answer: B. Full step-by-step solution below.

  1. ACH4
  2. BSF4
  3. C
  4. D

Correct answer: B

Solution

(b) For neutral molecules,
No. of electron pairs = No. of atoms bonded to it + 1/2 [Gp. no of central atom – Valency of central atom]
∴ For CH4, no. of e– pairs = = 4 (sp3 hybridisation)
For SF4, no. of e– pairs = = 5 (sp3 d hybridisation)
For ions,
No. of electron pairs = No. of atoms bonded to it + 1/2 [Gp. no. of central atom – Valency of central atom ± No. of electrons]
∴ For BF4–, no. e– pairs = = 4 (sp3 hybridisation)
For NH+4, no. of e– pairs = = 4 (sp3 hybridisation)

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