JEE · NEET Previous Year Question

In an reaction on chiral centres, there is

Topic: NEET PYQ

Answer: A. Full step-by-step solution below.

  1. Ainversion more than retention leading to partial racemisation
  2. B100% retention
  3. C100% inversion
  4. D100% racemisation.

Correct answer: A

Solution

(a) The carbocation formed in the slow step beinghybridised is planar andattack of nucleophile may take place from either side resulting in amixture of products, one having the same configuration and other having inverted configuration. The isomer corresponding to inversion is presentin slight excess because also depends upon the degree of shielding of the front side of the reacting carbon.

More Haloalkanes & Haloarenes PYQs