JEE · NEET Previous Year Question

A vessel contains 100 liters of a liquid X. Heat is supplied to the liquid in such a fashion that, Heat given = change in enthalpy. The volume of the liquid increases by 2 liters. If the external pressure is one atm, and 202.6 Joules of heat were supplied then, [U - total internal energy]

Topic: JEE PYQ

Answer: D. Full step-by-step solution below.

  1. AU = 0,H = 0
  2. BU = + 202. 6J, H = + 202.6 J
  3. CU = – 202.6J, H = – 202.6J
  4. DU = 0, H = + 202.6J

Correct answer: D

Solution

(d) H = heat given. So, process is isobaric.
w = – (V) = – 1 × 2 litre.atm = – 202.6 J
Hence, q = 202.6 J = H. and E = q + w = 0.

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